• 专利标题:   Porous grapheme-manganese dioxide midline coaxial nanowire material for use as electrochemical supercapacitor electrode active material, comprises long and short graphene sheets and manganese dioxide nanowires.
  • 专利号:   CN104599857-A, CN104599857-B
  • 发明人:   HU P, MAI L, YAN M, SHUANG Y
  • 专利权人:   UNIV WUHAN TECHNOLOGY
  • 国际专利分类:   B82Y030/00, B82Y040/00, H01G011/36, H01G011/86
  • 专利详细信息:   CN104599857-A 06 May 2015 H01G-011/36 201555 Pages: 12 Chinese
  • 申请详细信息:   CN104599857-A CN10031856 22 Jan 2015
  • 优先权号:   CN10031856

▎ 摘  要

NOVELTY - A porous graphite/manganese dioxide midline coaxial nanowire material comprises long and short graphene sheets having a length of 10-40 m and a diameter of 40-160 nm and manganese dioxide nanowires having a diameter of 30-80 nm. USE - Porous graphene/ manganese dioxide midline coaxial nanowire material for use as an electrochemical supercapacitor electrode active material (claimed). ADVANTAGE - The porous graphene/ manganese dioxide midline coaxial nanowire material has higher specific capacity and better cycle stability and excellent electrochemical performance at high current charge and discharge conditions, can be prepared with less energy consumption and total mass of graphene of 2.2% in a simple manner. DETAILED DESCRIPTION - A porous graphite/manganese dioxide midline coaxial nanowire material comprises long and short graphene sheets having a length of 10-40 m and a diameter of 40-160 nm and manganese dioxide nanowires having a diameter of 30-80 nm, where the porous graphite/manganese dioxide midline coaxial nanowire material is prepared by dissolving potassium permanganate powder in deionized water, adding ammonium fluoride and stirring at room temperature for 10-20 minutes, adding graphite association dispersion liquid to the resulting solution, stirring for 10-15 minutes, transferring resulting solution to a hydrothermal reaction autoclave, taking out the solution, cooling to room temperature, soaking the resulting reduction product in hydrazine hydrate, repeatedly washed with anhydrous hexanol, drying resulting product to obtain a porous graphene/ manganese dioxide midline coaxial nanowire material. An INDEPENDENT CLAIM is also included for a method for preparing a porous graphene/manganese dioxide midline coaxial nanowire material comprising steps as above per se.