• 专利标题:   Anti-icing super-smooth polyurea coating for wind power blades, comprises modified isocyanate, polyether polyol, lubricant, modified graphene oxide slurry, chain extender, modified amino-terminated polyether, diluent, foaming agent, modified nano molybdenum disulfide and auxiliary agent.
  • 专利号:   CN113773732-A, CN113773732-B
  • 发明人:   SU C, XU Y, WANG N
  • 专利权人:   SUZHOU JISHENLONG NEW MATERIAL TECHNOLOGY CO LTD, SUZHOU JISHENLONG NEW MATERIAL TECHNOLOG
  • 国际专利分类:   C09D175/02, C09D007/62, C09D007/65, C09K003/18
  • 专利详细信息:   CN113773732-A 10 Dec 2021 C09D-175/02 202234 Chinese
  • 申请详细信息:   CN113773732-A CN11063078 10 Sep 2021
  • 优先权号:   CN11063078

▎ 摘  要

NOVELTY - Anti-icing super-smooth polyurea coating comprises component-A and component-B in a ratio of 1:1.5-2.1, where the component-A includes 30-55 pts. wt. modified isocyanate, 20-40 pts. wt. polyether polyol, 10-20 pts. wt. lubricant and 2-10 pts. wt. modified graphene oxide slurry. The component-B is composed of 10-28 pts. wt. chain extender, 40-55 pts. wt. modified amino-terminated polyether, 5-10 pts. wt. diluent, 1-5 pts. wt. foaming agent, 5-10 pts. wt. modified nano molybdenum disulfide and 1-5 pts. wt. auxiliary agent. USE - The anti-icing super-smooth polyurea coating is useful for wind power blades. ADVANTAGE - The coating has low surface energy, exhibits excellent hydrophobicity, and can form a super-smooth polyurea coating with high adhesion performance and anti-icing on the surface of wind power blades, can improve the shelf life of the coating, delays the crystallization process of droplets and reduce the adhesion of ice to the substrate after crystallization, so as to improve the power generation efficiency and shelf life of the fan. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is also included for preparing the anti-icing super-smooth polyurea coating, comprising (a) preparing modified isocyanate, modified graphene oxide slurry, modified amino-terminated polyether and modified nanometer molybdenum disulfide, mixing modified isocyanate and polyether polyol, and heating up to 60-90℃ and reacting for 3-4 hours to obtain polymer, adding lubricant and modified graphene oxide slurry into the polymer, stirring at 1800-2000 revolutions/minute for 4-5 hours to obtain component A, the NCO value of component A is preferably 12-15% and the viscosity of component A is 700-800 mPa.s, (b) mixing chain extender, modified amino-terminated polyether, diluent, foaming agent, and modified nano molybdenum disulfide, stirring at 1500-2000 revolutions/minute for 30-50 minutes, heating at 90-102℃ for 3-4 hours, adding auxiliary agent to the amino polymer, stirring at 1500-2000 revolutions/minute for 20-30 minutes to obtain component-B, and (c) mixing component A and component B uniformly at 60-80℃ in a dynamic mixing chamber, where the chain extender is diethyltoluenediamine, 3,3'-dichloro-4,4'-diaminodiphenylmethane, the diluent is propylene carbonate and n-butyl acetate, the foaming agent is azobisisobutyronitrile and N,N'-dimethyl-N,N'-dinitrosoterephthalamide, the auxiliary agent includes fluid Leveling, defoaming and dispersing agents.