• 专利标题:   Preparing composite material involves stirring graphene oxide suspension in ultrasonic device, and then adding ferric sulfate solution, vanadium and sodium silicate solution in ultrasonic device.
  • 专利号:   CN103833083-A, CN103833083-B
  • 发明人:   LI H, ZHENG J, ZHANG B, WANG X, ZHANG J, YUAN X
  • 专利权人:   UNIV CENT SOUTH
  • 国际专利分类:   C01B025/45, C01G049/00, H01M004/1397
  • 专利详细信息:   CN103833083-A 04 Jun 2014 C01G-049/00 201450 Pages: 7 Chinese
  • 申请详细信息:   CN103833083-A CN10104093 20 Mar 2014
  • 优先权号:   CN10104093

▎ 摘  要

NOVELTY - Composite material preparation involves stirring graphene oxide suspension (1-3%) in an ultrasonic device at 20-40 kilo Hertz for 0.2-2 hours, and then ferric sulfate solution (0.08-0.12mol/l), vanadium (0.16-0.24mol/l) and sodium silicate solution are added in an ultrasonic device, and then obtained mixture is stirred at 50-400 revolutions/minute. The obtained mixture is mixed with ammonium hydroxide for 0.5-4 hours, and then vanadic acid and graphene oxide in mass ratio of 100:5-10 are added in reaction vessel. Polyaniline is added in reaction vessel. USE - Method for preparing composite material (claimed). ADVANTAGE - The method enables to prepare composite material that has excellent electrochemical properties. DETAILED DESCRIPTION - Composite material preparation involves stirring graphene oxide suspension (1-3%) in an ultrasonic device at 20-40 kilo Hertz for 0.2-2 hours, and then ferric sulfate solution (0.08-0.12mol/l), vanadium (0.16-0.24mol/l) and sodium silicate solution are added in an ultrasonic device, and then obtained mixture is stirred at 50-400 revolutions/minute. The obtained mixture is mixed with ammonium hydroxide for 0.5-4 hours, and then vanadic acid and graphene oxide in mass ratio of 100:5-10 are added in reaction vessel. Polyaniline is added in reaction vessel, where molar ratio of polyaniline and vanadic acid is 5-10:100 and then mixture is stirred for 0.2-0.6 hours at 150-250 revolutions/minute. The obtained mixture is filtered and washed to obtain product, which is dried to obtain desired product.