• 专利标题:   High-performance palladium-zinc alloy carbon/zinc oxide composite material used for acetylene reaction selective hydrogenation, comprises zinc oxide carrier and graphene carbon layer, prepared by.
  • 专利号:   CN109046344-A
  • 发明人:   YANG L, GUO Y, LIU H, XIA L
  • 专利权人:   UNIV LIAONING
  • 国际专利分类:   B01J023/60, C07C005/09, C07C011/04
  • 专利详细信息:   CN109046344-A 21 Dec 2018 B01J-023/60 201921 Pages: 10 Chinese
  • 申请详细信息:   CN109046344-A CN10789232 18 Jul 2018
  • 优先权号:   CN10789232

▎ 摘  要

NOVELTY - A high-performance palladium-zinc alloy carbon/zinc oxide composite material comprises zinc oxide carrier and graphene carbon layer coated onto supported palladium-zinc alloy. USE - High-performance palladium-zinc alloy carbon/zinc oxide composite material used for acetylene reaction selective hydrogenation (claimed). ADVANTAGE - The product exhibits excellent half of acetylene selective hydrogenation performance. DETAILED DESCRIPTION - INDEPENDENT CLAIMS are included for: (1) preparation of high-performance palladium-zinc alloy carbon/zinc oxide composite material comprising dispersing zinc oxide in deionized water, adding palladium(II) nitrate aqueous solution and sodium carbonate solution, stirring at 80-100 degrees C for 1-3 hours, filtering, taking solid, drying at 70-90 degrees C, pumping hydrogen, reducing at 180-220 degrees C for 1-3 hours to obtain palladium/zinc oxide, spreading into porcelain boat, taking ethylbenzene, pumping argon gas at flow rate of 50-200 mL/minute, heating palladium/zinc oxide at 600-700 degrees C, adding ethylbenzene, and heating at 130-150 degrees C for 2-5 minutes; and (2) application of high-performance palladium-zinc alloy carbon/zinc oxide composite material comprising mixing with quartz sand, passing acetylene at flow rate of 180000 mL/g.h, and reacting at 100-200 degrees C.