• 专利标题:   Carbon-supported bimetallic single-atom catalyst comprises a carbon support and active metals, which are respectively two kinds of metals e.g. iridium, rhodium, platinum, ruthenium, gold, silver, rhenium, cobalt, nickel, chromium and tin.
  • 专利号:   CN114522682-A
  • 发明人:   NING L, YUAN Q, FENG S, SONG X, LI X, DING Y
  • 专利权人:   CAS DALIAN CHEM PHYSICAL INST
  • 国际专利分类:   B01J023/46, B01J023/50, B01J023/52, B01J023/62, B01J023/652, B01J023/656, B01J023/89, C07C067/36, C07C069/14
  • 专利详细信息:   CN114522682-A 24 May 2022 B01J-023/46 202288 Chinese
  • 申请详细信息:   CN114522682-A CN11321179 23 Nov 2020
  • 优先权号:   CN11321179

▎ 摘  要

NOVELTY - Carbon-supported bimetallic single-atom catalyst comprises a carbon support and active metals N and M, where N and M are respectively two kinds of metals e.g. iridium, rhodium, platinum, ruthenium, gold, silver, rhenium, cobalt, nickel, chromium and tin, and N and M are different, metals N and M are atomically monodispersed on the surface of carbon supports in the form of mononuclear complexes containing carbonyl and halogen ligands, respectively. USE - Used as carbon-supported bimetallic single-atom catalyst. ADVANTAGE - The catalyst has simple preparation process and strong universality, is highly dispersed and stability, and can be prepared with high-capacity in batches. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is also included for preparation method of the catalyst, comprising (i) preparing carbon support-supported bimetallic N and M nanoparticles, where the specific process is: impregnating carbon support with equal volume of precursor solution containing bimetallic N and M, calcining in inert gas (at 300-500°C), and reducing by hydrogen (at 300-500°C), and supporting the nano-alloy particles containing metal N and M on carbon carrier; and (ii) reusing at least one of carbon monoxide and halogen, hydrohalic acid or halogenated hydrocarbon to react with the alloy nanoparticles of metal N and M at the same time, and carry outing in-situ atomic-level monodispersion treatment to obtain carbon-supported bimetallic single-atom catalysts.