• 专利标题:   Preparing a graphene composite fiber comprises e.g. taking raw materials, preparing graphene poly(p-phenylene benzobisoxazole primary filaments, modifying the surface of the graphene PBO fiber and preparing coating slurry, carrying out sizing treatment, drying and winding.
  • 专利号:   CN114086273-A
  • 发明人:   MA L, SHA X, SHA Y
  • 专利权人:   NANTONG QIANGSHENG GRAPHENE TECHNOLOGY
  • 国际专利分类:   D01F001/10, D01F011/12, D01F011/14, D01F006/88
  • 专利详细信息:   CN114086273-A 25 Feb 2022 D01F-006/88 202238 Chinese
  • 申请详细信息:   CN114086273-A CN11548503 17 Dec 2021
  • 优先权号:   CN11548503

▎ 摘  要

NOVELTY - Preparing a graphene composite fiber comprises (i) taking raw materials, (ii) adding 4, 6-diaminoresorcinol hydrochloride, terephthalic acid, polyphosphoric acid, phosphorus pentoxide, stannous chloride, a graphene material and a modifier into a reaction kettle, gradually heating under the protection of nitrogen, reacting, vacuumizing and cooling to obtain a graphene (poly (p-phenylene benzobisoxazole) fiber (PBO) polymer, placing the resultant graphene PBO polymer into a double-screw extruder, carrying out melt spinning, primarily stretching a graphene PBO filament, drying and winding to obtain the graphene PBO filament fiber, (iii) immersing the resultant graphene PBO filament fibers into an acid solution and completing the etching treatment on the surfaces of the fibers, and (iv) preparing coating slurry, then placing the resultant modified graphene PBO fiber into a slurry tank, carrying out sizing treatment, drying and winding to obtain the product. USE - The method is useful for preparing a graphene composite fiber. ADVANTAGE - The composite fiber: has high strength, excellent anti-cutting and anti-ultraviolet performance. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is also included for graphene composite fiber prepared by the above mentioned method.