• 专利标题:   Preparing graphene nano-rod comprises preparing carbon material and graphene oxide, adding sulfuric acid/potassium permanganate, filtering mixture by micro-pore filter membrane, and dissolving transparent solution in diethyl ether/ethanol.
  • 专利号:   CN103738942-A, CN103738942-B
  • 发明人:   FAN T, LIU Y, MIN Y, SONG J, TONG S, ZHANG L
  • 专利权人:   NANJING XINYUE MATERIAL TECHNOLOGY CO, YANCHENG ZENGCAI TECHNOLOGY CO LTD
  • 国际专利分类:   B82Y030/00, B82Y040/00, C01B031/04
  • 专利详细信息:   CN103738942-A 23 Apr 2014 C01B-031/04 201461 Pages: 9 Chinese
  • 申请详细信息:   CN103738942-A CN10563566 14 Nov 2013
  • 优先权号:   CN10563566

▎ 摘  要

NOVELTY - Preparing graphene nano-rod comprises preparing carbon material and graphene oxide by Hummers method, adding sulfuric acid/potassium permanganate under low ice bath condition, filtering the mixture with micro-pore filtering membrane to obtain light yellow transparent solution, dissolving transparent solution in mixed liquid of diethyl ether/ethanol to form floc, then filtering and washing to obtain nanoscale graphene quantum dots and nano-graphene sheet, adding graphene oxide and sulfuric acid/potassium permanganate, and ultrasonically reflowing in a microwave reactor. USE - The method is useful for preparing graphene nano-rod (claimed), which is useful as transparent electrode in an intelligent window, a super capacitor, a micro super capacitor, lithium battery, solar battery and FET. DETAILED DESCRIPTION - Preparing graphene nano-rod comprises preparing carbon material and graphene oxide by Hummers method, adding sulfuric acid/potassium permanganate under low ice bath condition, filtering the mixture with micro-pore filtering membrane to obtain light yellow transparent solution, dissolving transparent solution in mixed liquid of diethyl ether/ethanol to form floc, then filtering and washing to obtain nanoscale graphene quantum dots and nano-graphene sheet, adding graphene oxide and sulfuric acid/potassium permanganate in a volume ratio of 3:1-7:1, ultrasonically reflowing in a microwave reactor, keeping dialysis solution under alkaline condition to obtain graphene quantum dots, adding reducing agent, graphene quantum dots and nano-graphene sheet with alkaline solution, and then annealing at high temperature.