• 专利标题:   High first-efficiency graphene composite silicon-carbon cathode material comprises e.g. silicon-carbon particles with core-shell structure and graphene micro-sheet composite, where outer layer of silicon-carbon particles with core-shell structure is inorganic carbon layer.
  • 专利号:   CN114400310-A
  • 发明人:   YOU J, MA C, LANG Q, LIU Z, JI J, PENG X
  • 专利权人:   NINGBO INST MATERIALS TECHNOLOGY ENG C
  • 国际专利分类:   B82Y030/00, C01B032/05, C01B032/194, C01B033/021, C01B033/32, H01M010/0525, H01M004/36, H01M004/38, H01M004/62
  • 专利详细信息:   CN114400310-A 26 Apr 2022 H01M-004/36 202288 Chinese
  • 申请详细信息:   CN114400310-A CN10042443 14 Jan 2022
  • 优先权号:   CN10042443

▎ 摘  要

NOVELTY - High first-efficiency graphene composite silicon-carbon cathode material comprises silicon-carbon particles with a core-shell structure and graphene micro-sheet composite. The outer layer of the silicon-carbon particles with core-shell structure is an inorganic carbon layer and the inner layer is a silicate-coated nano-silicon particles. The silicon carbon particles with core-shell structure and the graphene microplates are compounded by the cross-connection effect of silicate. USE - Used as high first-efficiency graphene composite silicon-carbon cathode material. ADVANTAGE - The material: has excellent lithium-ion conductivity and structural stability; synergistically reduces the expansion of the material; improves the conductivity of the material; inhibits volume expansion of the nano-silicon in the primary particles during the cycle through the multi-level coating structure of the silicate layer and the inorganic carbon layer, and cross-connection effect of the silicate components; reduces damage to secondary particles caused by volume expansion during charging and discharging; and ensures that the cathode material has high gram capacity and excellent cycle performance. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is also included for battery.