• 专利标题:   Preparing reduced graphene flexible conductive film and three-step moderate reduction used in e.g. flexible film sensor by ultrasonically cleaning polyethylene terephthalate (PET) flexible base film, adding graphene oxide solution, reacting, surface-reducing graphene oxide film and drying.
  • 专利号:   CN115246949-A
  • 发明人:   TIAN Y, GUO N, GENG H
  • 专利权人:   UNIV TIANJIN POLYTECHNIC
  • 国际专利分类:   C01B032/184, C01B032/194, C08J007/06, C08L067/02
  • 专利详细信息:   CN115246949-A 28 Oct 2022 C08J-007/06 202204 Chinese
  • 申请详细信息:   CN115246949-A CN10456565 27 Apr 2021
  • 优先权号:   CN10456565

▎ 摘  要

NOVELTY - Preparing reduced graphene flexible conductive film and three-step moderate reduction comprises ultrasonically cleaning the polyethylene terephthalate (PET) flexible base film with distilled water and acetone and drying, weighing a certain amount of reducing substance, adding to a certain concentration of graphene oxide solution, placing into a constant temperature water bath heating stirrer, reacting for a period of time to obtain preliminary reduced graphene oxide, evenly coating the I-rGO solution on the treated PET substrate by scraping method, solidifying to form a film, surface-reducing the graphene oxide film for a period of time using a configured reducing solution of a certain concentration in an environment higher than room temperature, repeating the reduction operation once to obtain a surface-reduced graphene oxide (S-rGO) film, immersing the Al-rGO film in acid for a period of time, washing and drying repeatedly and obtaining a stable structure and low surface resistance. USE - The method is useful for preparing reduced graphene flexible conductive film and three-step moderate reduction used in flexible film sensor, flexible film electrode, antistatic film, electronic, energy, biological and medicine fields. ADVANTAGE - The method: provides the flexible conductive film with excellent conductive performance, low surface resistance, good mechanical performance, and good application value in the field of flexible film electrode; is safe, simple and fast; can be produced in large scale and has good film electric performance, when the light transmittance is 54% and the surface resistance is only 6.23 k/sq. DETAILED DESCRIPTION - Preparing reduced graphene flexible conductive film and three-step moderate reduction comprises ultrasonically cleaning the polyethylene terephthalate (PET) flexible base film with distilled water and acetone and drying, weighing a certain amount of reducing substance, adding to a certain concentration of graphene oxide (GO) solution, placing into a constant temperature water bath heating stirrer, reacting for a period of time to obtain preliminary reduced graphene oxide (I-rGO), evenly coating the I-rGO solution on the treated PET substrate by scraping method at a certain temperature, solidifying to form a film, surface-reducing the graphene oxide film for a period of time using a configured reducing solution of a certain concentration in an environment higher than room temperature, repeating the reduction operation once to obtain a surface-reduced graphene oxide (S-rGO) film, using vacuum evaporation technology to cover the surface of the SrGO film with metal aluminum coating to obtain an Al-rGO film, immersing the Al-rGO film in acid for a period of time, washing and drying repeatedly and obtaining a stable structure and low surface resistance.