• 专利标题:   Graphene-coated solid acid catalyst useful for catalytic nitration of aromatic hydrocarbon compounds.
  • 专利号:   CN114345341-A
  • 发明人:   JIN G, ZHANG R, HUANG W, ZHAO S, REN L, JI F, YANG Z
  • 专利权人:   CHINA PETROLEUM CHEM CORP, SINOPEC NANJING CHEM RES INST CO LTD
  • 国际专利分类:   B01J021/06, B01J021/18, B01J023/745, B01J023/75, B01J035/10, B01J037/03, B01J037/08, C07C201/08, C07C205/06
  • 专利详细信息:   CN114345341-A 15 Apr 2022 B01J-023/745 202281 Chinese
  • 申请详细信息:   CN114345341-A CN11090703 13 Oct 2020
  • 优先权号:   CN11090703

▎ 摘  要

NOVELTY - Graphene-coated solid acid catalyst having a specific surface area of 800-1000 m2/g, a pore size of 50-100 nm of ≥ 80%, and an acidity of 4-6 mmol H+/g, is claimed. USE - The catalyst is useful for catalytic nitration of aromatic hydrocarbon compounds (claimed). ADVANTAGE - The catalyst: has high activity, stable performance, wide application range, obvious application and popularization value. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is also included for preparing the catalyst, comprising (i) adding aqueous ammonia atomization to metal salt aqueous solution under the action of super-gravity to precipitate, then washing, drying and milling to obtain 20-30 nm particles A, (ii) adding particles A obtained in the step (i) into polycyclic aromatic hydrocarbons and a complexing agent to fully mix, and carbonizing at a high temperature to obtain a graphene-coated intermediate product B, and (iii) subjecting graphene-coated intermediate product B obtained in the step (ii) to sulfuric acid circulation soaking, filtering, drying and roasting to obtain the finished product.