• 专利标题:   Mechanical-blending of graphene oxide/white carbon black/rubber nanocomposite, involves mixing graphene oxide and rubber masterbatch in internal mixer for preset time, adding white carbon black and coupling agent, and mixing.
  • 专利号:   CN103275368-A, CN103275368-B
  • 发明人:   ZHANG F, LIU L, MAO Y, WEN S
  • 专利权人:   UNIV BEIJING CHEM TECHNOLOGY
  • 国际专利分类:   C08K003/04, C08K003/36, C08K009/04, C08K009/06, C08L011/00, C08L023/16, C08L023/22, C08L027/12, C08L007/00, C08L083/04, C08L009/00, C08L009/02, C08L009/06
  • 专利详细信息:   CN103275368-A 04 Sep 2013 C08L-009/06 201426 Chinese
  • 申请详细信息:   CN103275368-A CN10157282 23 Feb 2012
  • 优先权号:   CN10157282

▎ 摘  要

NOVELTY - Graphene oxide and rubber masterbatch are mixed in an internal mixer for 1-5 minutes. White carbon black and coupling agent, or white carbon black surface-modified with coupling agent are added and mixed for 1-20 minutes to obtain a graphene oxide/white carbon black/rubber nanocomposite. Or, white carbon black and rubber masterbatch are mixed, and then graphene oxide and interface agent are added and mixed. Or, all the components are co-mixed for 1-20 minutes. USE - Mechanical-blending of graphene oxide/white carbon black/rubber nanocomposite (claimed). ADVANTAGE - The method provides graphene oxide/white carbon black/rubber nanocomposite in which graphene and white carbon black are inserted with each other. Hence, self-aggregation of the two fillers is effectively suppressed and composite having excellent dispersibility is obtained. The composite has high modulus, low rolling resistance, and excellent wear resistance and tear resistance. Because of the lamellar structure and good self-recovery capability of graphene oxide, the rubber material has excellent gas-barrier property and self-healing property. The method is simple, easy and economical. DETAILED DESCRIPTION - Graphene oxide and rubber masterbatch are mixed in an internal mixer for 1-5 minutes. White carbon black and coupling agent, or white carbon black surface-modified with coupling agent are added and mixed for 1-20 minutes to obtain a graphene oxide/white carbon black/rubber nanocomposite. Or, white carbon black and rubber masterbatch are mixed, and then graphene oxide and interface agent are added and mixed. Or, rubber masterbatch is mixed in an internal mixer, and white carbon black surface-modified with coupling agent and graphene oxide, or carbon black, coupling agent, graphene oxide, and interface agent are added and mixed for 1-20 minutes. Or, all the components are co-mixed for 1-20 minutes.