▎ 摘　　要

NOVELTY - Metal complex in any physical form comprises the product of the reaction of at least one compound comprising macrocycles and/or isoprenoids and/or linear tetrapyrroles and at least one metal alkoxide obtainable by mechanochemistry (grinding or milling) under solvent-free conditions, where the mechanochemistry includes the use of a mechanical or hand mortar and pestle, high speed milling, ball milling, attrition milling, planetary milling or extrusion. USE - The complex is useful: in composition in the form of an emulsion (water in oil or oil in water), miniemulsion, microemulsion, suspension or dispersion; in cosmetic, sunscreen, pharmaceutical food, staining, painting, coating, superhydrophobic coating/textile/surface composition; for fabricating sunscreen/UV filter/UV absorber product to prevent premature aging of the keratinous material, to prevent skin or hair disorders, to prevent photodegradation or degradation of a compound/material/surface; as a dye/pigment itself; or in combination with other dyes/pigments or compounds as a textile dye, keratinous dye, wood/paper dye, food dye, pharmaceutical dye in powder form or as colloids; as catalyst for reactions and polymerizations; as additives in semiconductors, conductors or superconductors; as DNA/RNA binding agent; as DNA/RNA coating technique or any other coating technique having superhydrophobic/hydrophobic coating; and for preparing materials or surfaces or article (all claimed). Test details are described but no results given. ADVANTAGE - The complex: prepares materials or surfaces or article of manufacture with other properties, e.g. superamphiphobic or superamphiphilic properties and/or antiviral/antifugal/antibactericide properties; and selective extracts biomolecules from natural resources by using aqueous and/or organic solvents. DETAILED DESCRIPTION - INDEPENDENT CLAIMS are also included for: (1) fabricating (P1) the metal complexes, comprising simultaneously or sequentially (a) mixing (or adding) the metal alkoxide compound with (into) the macrocycle compound and/or at least one isoprenoid compound and/or at least one linear tetrapyrrole in a container (or a substrate having keratinaceous fiber or other material), (b) performing mechanochemistry (e.g. by grinding or by milling or by hand macerating the reactants until an intermediate metal complex material (or intermediate tone) is obtained or a finished material is obtained and either, (c) further grinding or milling the intermediate metal complex material to obtain the finished metal complex and optionally letting rest the final material (coloring matter or tone), where the powder obtained is a colored material with colors having blue, red, yellow, orange, violet, pink, green brown or black, (d) optionally further processing the intermediate metal complex material (or intermediate tone) (e.g. by extrusion, by blending, by bending brake, by hydraulic press, by thermoforming or by injection molding) until the desired material/article is obtained with the desired color; (2) forming (M1) the metal complex or compound or material or an article, comprising reacting at least one macrocycles and/or at least one isoprenoid and/or at least one linear tetrapyrrole with at least one metal alkoxide by solvent-free mechanochemistry (grinding or milling), where the physical form of the colored material both the intermediate metal complex and the finished metal complex, having powder, presscake, granule, chip or lake, liquid, liquid dispersion, colloids, paste, liquid crystals or flush color is tuned by the conditions of the mechanochemical reaction having the type of the reactants, the proportion of the reactants, the temperature, the milling/grinding time, the speed, the ball/weight ratio, the milling media, the presence or the absence of additives; (3) metal complex obtained by the process; (4) composition in the form of an emulsion (water in oil or oil in water), miniemulsion, microemulsion, suspension or dispersion comprising the metal complex, preferably where the metal complex is encapsulated in a polymer matrix; (5) cosmetic, sunscreen, pharmaceutical food, staining, painting, coating, superhydrophobic coating/textile/surface composition comprising the metal complex compound or material; (6) fabricating (P2) a sunscreen/UV filter/UV absorber product to prevent premature aging of the keratinous material, to prevent skin or hair disorders, to prevent photodegradation or degradation of a compound/material/surface; and (7) coloring (M2) material comprising applying to the material which is colored or contacting the material which is colored with, in any order, successively or simultaneously, (a3) at least one compound having macrocycles and/or isoprenoids and/or linear tetvapyrvole, (b3) at least one metal alkoxide, and (c3) optionally at least one additive, under conditions that the material which is colored is absorbed or adsorbed with the compound (a3) and left under conditions that no lateral reactions take place or lateral reactions are minimized e.g. by solvent-free conditions, and then the compound (b3), the metal alkoxide, is provided, and by using the hand or the fingers, or a pestle or a comb as pestle tool and the other hand as a container to perform a mechanochemical reaction having the material is colored as substrate in between, where the additive (c) can be added to at least one compound (a) or at least one metal alkoxide if an additive having an aqueous or organic solvent is used to enhance the diffusion of compound (a) or (b), it is preferably let evaporating or drying in the substrate before the next compound is added and if an aqueous or organic herbal/algae/microalgae/fungus/animal compound or material is used, the solvent is let to dry out of the substrate before the next component is added, optionally, if the complex is formed in an external container, it can be applied to the substrate or material is colored and then the method of coloring material of the present claim can be carried out.