• 专利标题:   Double-layer capsule wall energy storage temperature-regulating microcapsule comprises capsule core, first capsule wall wrapping capsule core, and second capsule wall wrapping first capsule wall, where first capsule wall is polymethyl methacrylate modified with allyl methacrylate.
  • 专利号:   CN113913160-A
  • 发明人:   ZHAO J
  • 专利权人:   QINGDAO NIXIMI BIOTECHNOLOGY CO LTD
  • 国际专利分类:   B01J013/14, C09K005/06, D01F001/10, D01F006/54
  • 专利详细信息:   CN113913160-A 11 Jan 2022 C09K-005/06 202265 Chinese
  • 申请详细信息:   CN113913160-A CN11320145 09 Nov 2021
  • 优先权号:   CN11320145

▎ 摘  要

NOVELTY - Double-layer capsule wall energy storage temperature-regulating microcapsule comprises a capsule core, a first capsule wall wrapping the capsule core, and a second capsule wall wrapping the first capsule wall. The capsule core is a phase change material. The first capsule wall is polymethyl methacrylate modified with allyl methacrylate. The second capsule wall is polyacrylonitrile. USE - Used as double-layer capsule wall energy storage temperature-regulating microcapsule. ADVANTAGE - The method: increases the structural stability of the microcapsules; improves the compatibility of the double-walled energy storage and temperature-regulating microcapsules with the polyacrylonitrile spinning solution; uniformly disperses the double-walled energy storage and temperature regulation microcapsules in the polyacrylonitrile spinning solution; increases the stability of the polyacrylonitrile fiber; and improves the stability of the energy storage and temperature regulation of the polyacrylonitrile fiber. DETAILED DESCRIPTION - INDEPENDENT CLAIMS are also included for: (1) preparing the microcapsules, comprising (1) mixing phase change material, methyl methacrylate, allyl methacrylate, emulsifier, first initiator and water to obtain an emulsion, subjecting the obtained emulsion to a first emulsion polymerization reaction to obtain primary energy storage temperature-regulating microcapsules, where the primary energy storage temperature-regulating microcapsules include a capsule core and a first capsule wall surrounding the capsule core, the first capsule wall is polymethyl methacrylate modified with allyl methacrylate, and (2) mixing the primary energy storage temperature-regulating microcapsules with acrylonitrile to obtain a mixed emulsion, mixing the mixed emulsion and the second initiator, and carrying out second emulsion polymerization reaction to obtain the double-walled energy storage and temperature-regulating microcapsules; and (2) preparing the polyacrylonitrile fiber, comprising mixing double-layer capsule wall energy storage and temperature-regulating microcapsules, the antistatic agent dispersion liquid and the original polyacrylonitrile spinning solution to obtain a spinning mother liquor, where the original polyacrylonitrile spinning solution comprises sodium thiocyanate and polyacrylonitrile, mixing the spinning mother liquor with the original polyacrylonitrile spinning solution to obtain a polyacrylonitrile spinning solution, and spinning the polyacrylonitrile spinning solution to obtain the polyacrylonitrile fiber.