• 专利标题:   Preparing high-frequency transmission liquid crystal polymer film useful for e.g. electronics, comprises acetating monomers, crushing high-temperature polymerization of acetylated monomer and phenolic resin, mixing liquid crystal copolyester, cooling, slitting longitudinally and transversely.
  • 专利号:   CN113502040-A, CN113502040-B, US2023026810-A1
  • 发明人:   XU L, YU R, ZHANG D
  • 专利权人:   NINGXIA QINGYAN POLYMER NEW MATERIAL CO, NINGXIA QINGYAN POLYMER NEW MATERIAL CO
  • 国际专利分类:   C09K019/38, C08G063/06, C08J005/18, C08K005/5419, C08K005/5435, C08K005/544, C08K003/36, C08K003/04, C08K007/14, C08L067/04, C08G063/83, C08J003/12
  • 专利详细信息:   CN113502040-A 15 Oct 2021 C08L-067/04 202198 Chinese
  • 申请详细信息:   CN113502040-A CN10838652 23 Jul 2021
  • 优先权号:   CN10838652

▎ 摘  要

NOVELTY - Preparing high-frequency transmission liquid crystal polymer (LCP) film, comprises (i)acetating monomers separately to obtain acetylated monomers; (ii) crushing high-temperature polymerization of acetylated monomer, phenolic resin, acetic anhydride and zinc acetate to obtain liquid crystal copolyester; (iii) mixing liquid crystal copolyester, inorganic filler, silane coupling agent and glass fiber ball mill to obtain a mixture, melting and plasticizing the mixture, cooling to form a film, stretch, wind, and slitting longitudinally and transversely simultaneously to obtain a high-frequency transmission LCP film, where, the monomer is at least one of p-hydroxybenzoic acid, acetylated 2-hydroxy-6-naphthoic acid, acetylated 4-hydroxy-3-methoxybenzoic acid and acetylated 4-hydroxyphenylpyruvate. USE - The film is useful for electronics, electrical, optical fibers and 5G communications. ADVANTAGE - The method enhances its mechanical properties and reduce its dielectric loss; ensures LCP films with low dielectric constant and low dielectric loss factor DETAILED DESCRIPTION - An INDEPENDENT CLAIM is also included for high-frequency transmission LCP film, prepared by the method as mwntioned abovr, where thickness of the high-frequency transmission LCP film is 50-70 mum and the electric constant is lower than 2.6, and the dielectric loss factor is lower than 0.01.