• 专利标题:   Preparation of nitrogen-doped graphene by adding graphite oxide to deionized water, ultrasonically processing, adding aniline, mixing, adding benzoyl peroxide, stirring, filtering, cleaning, drying, heating, incubating and cooling.
  • 专利号:   CN103991861-A
  • 发明人:   LIU D, WANG Y, ZHONG H, ZHOU M
  • 专利权人:   OCEANS KING LIGHTING SCI TECHNOLOGY CO, SHENZHEN OCEANS KING LIGHTING ENG CO LTD, SHENZHEN OCEANS KING LIGHTING SCI TECH
  • 国际专利分类:   C01B031/04
  • 专利详细信息:   CN103991861-A 20 Aug 2014 C01B-031/04 201475 Pages: 10 Chinese
  • 申请详细信息:   CN103991861-A CN10054663 20 Feb 2013
  • 优先权号:   CN10054663

▎ 摘  要

NOVELTY - Preparation of nitrogen-doped graphene comprises adding graphite oxide to deionized water at a mass volume ratio of 0.5-1 mg: 1 ml, ultrasonically processing for 1 hour, adding aniline, ultrasonically mixing the suspension, lowering temperature at 0-10 degrees C, placing the suspension in hydrochloric acid and maintaining the pH value at 3-5, adding benzoyl peroxide, stirring for 12-20 hours, filtering, cleaning, drying to obtain oxidized graphene-polyaniline mixture, heating mixture to 750-1000 degrees C under oxygen-free atmosphere, incubating for 0.5-2 hours, and cooling. USE - Method for preparing nitrogen-doped graphene (claimed). ADVANTAGE - The prepared graphene has high nitrogen content. DETAILED DESCRIPTION - Preparation of nitrogen-doped graphene comprises adding graphite oxide to deionized water at a mass volume ratio of 0.5-1 mg: 1 ml, ultrasonically processing for 1 hour, adding aniline, ultrasonically mixing the suspension, lowering temperature at 0-10 degrees C, placing the suspension in hydrochloric acid and maintaining the pH value at 3-5, adding benzoyl peroxide, stirring for 12-20 hours, filtering, cleaning, drying to obtain oxidized graphene-polyaniline mixture, heating mixture to 750-1000 degrees C under oxygen-free atmosphere, incubating for 0.5-2 hours, and cooling. The mass ratio of aniline and graphite oxide is 0.5: 0.4. The mass ratio of benzoyl peroxide and aniline is 0.005: 0.5-0.001: 0.4.