• 专利标题:   Preparing chemical oxygen demand degradation catalyst for organic wastewater, by dissolving ferric chloride hexahydrate and sodium acetate in solvent, adding tetrabutyl titanate, adding mixed solution to PTFE liner of reactor, and drying.
  • 专利号:   CN112237915-A
  • 发明人:  
  • 专利权人:   NANJING KAIXUAN CHEM TECHNOLOGY CO LTD
  • 国际专利分类:   B01J023/745, C02F001/78, C02F101/38
  • 专利详细信息:   CN112237915-A 19 Jan 2021 B01J-023/745 202114 Pages: 6 Chinese
  • 申请详细信息:   CN112237915-A CN10643839 17 Jul 2019
  • 优先权号:   CN10643839

▎ 摘  要

NOVELTY - Method for preparing chemical oxygen demand degradation catalyst for organic wastewater involves (a) dissolving ferric chloride hexahydrate and sodium acetate in the solvent, mixing evenly, adding to the hydrothermal kettle, stirring and reacting for 5-10 hours to obtain iron oxide nanoparticles, (b) adding tetrabutyl titanate to absolute ethanol, adding iron oxide nanoparticles and surfactant, and stirring for 2-5 hours to obtain a mixed solution, (c) adding the mixed solution to the PTFE liner of the reactor, and sealing the reaction at 160-180 degrees C for 8-12 hours to obtain a titanium dioxide/ferrous oxide composite, (d) preparing reduced graphene oxide by ultrasonic-assisted Hummer method, ultrasonically dispersing, adding titanium dioxide/ferrous oxide composite, cooling to room temperature, centrifuging, washing and drying, and (e) drying the material, roasting and keeping warm, and cooling to room temperature to obtain the product. USE - The method is used for preparing chemical oxygen demand degradation catalyst, which is used for treating organic wastewater (claimed). ADVANTAGE - The chemical oxygen demand degradation catalyst has a high degradation rate for various organic substances in water and excellent degradation effect, and is suitable for industrial wastewater treatment. DETAILED DESCRIPTION - Method for preparing chemical oxygen demand degradation catalyst for organic wastewater involves (a) dissolving ferric chloride hexahydrate and sodium acetate in the solvent, mixing evenly, adding to the hydrothermal kettle, stirring and reacting for 5-10 hours to obtain iron oxide nanoparticles, (b) adding tetrabutyl titanate to absolute ethanol, adding iron oxide nanoparticles and surfactant, and stirring for 2-5 hours to obtain a mixed solution, (c) adding the mixed solution to the PTFE liner of the reactor, and sealing the reaction at 160-180 degrees C for 8-12 hours to obtain a titanium dioxide/ferrous oxide composite, (d) preparing reduced graphene oxide by ultrasonic-assisted Hummer method, ultrasonically dispersing, adding titanium dioxide/ferrous oxide composite, and stirring for 2-5 hours, transferring the dispersion to the reaction kettle, increasing the temperature, after 8-12 hours of reaction, cooling to room temperature, centrifuging, washing and drying, and (e) drying the material, roasting and keeping warm, and cooling to room temperature to obtain the product.