• 专利标题:   Producing metal matrix nanocomposite by preparing graphene dispersion, bringing the graphene dispersion in physical contact with solid substrate surface, and depositing layer of metal or metal alloy onto surfaces of aligned graphene sheets.
  • 专利号:   US2019292672-A1
  • 发明人:   ZHAMU A, LIN Y, JANG B Z
  • 专利权人:   NANOTEK INSTR INC
  • 国际专利分类:   B82B003/00, C22C019/03, C22C026/00, C22C009/00, C23C018/16, C25D001/00, C25D003/12, C25D003/38, F28F021/02, F28F021/08
  • 专利详细信息:   US2019292672-A1 26 Sep 2019 C25D-001/00 201978 Pages: 27 English
  • 申请详细信息:   US2019292672-A1 US935636 26 Mar 2018
  • 优先权号:   US935636

▎ 摘  要

NOVELTY - A metal matrix nanocomposite is produced by (A) preparing a graphene dispersion comprising multiple discrete graphene sheets dispersed in liquid adhesive resin; (B) bringing the graphene dispersion in physical contact with a solid substrate surface and aligning graphene sheets along a planar direction of substrate surface where graphene sheets are bonded to and supported by substrate surface; (C) depositing a layer of metal or metal alloy having a thickness of 0.5 nm-10 mu m, onto surfaces of aligned graphene sheets to form a layer of metal-coated graphene sheets supported by substrate surface, where metal or metal alloy contains a transition metal, aluminum (Al), magnesium (Mg), tin (Sn), indium (In), lead (Pb), and/or alloy; and (D) separating the layer of metal-coated graphene sheets from substrate surface and consolidating the layer of metal-coated graphene sheets into a metal matrix nanocomposite. USE - Production of metal matrix nanocomposite. ADVANTAGE - The method provides metal matrix nanocomposite that exhibits a combination of exceptional tensile strength, modulus, thermal conductivity, and/or electrical conductivity. DETAILED DESCRIPTION - A metal matrix nanocomposite is produced by (A) preparing a graphene dispersion comprising multiple discrete graphene sheets dispersed in liquid adhesive resin; (B) bringing the graphene dispersion in physical contact with a solid substrate surface and aligning graphene sheets along a planar direction of substrate surface where graphene sheets are bonded to and supported by substrate surface; (C) depositing a layer of metal or metal alloy having a thickness of 0.5 nm-10 mu m, onto surfaces of aligned graphene sheets to form a layer of metal-coated graphene sheets supported by substrate surface, where metal or metal alloy contains a transition metal, aluminum (Al), magnesium (Mg), tin (Sn), indium (In), lead (Pb), and/or alloy; and (D) separating the layer of metal-coated graphene sheets from substrate surface and consolidating the layer of metal-coated graphene sheets into a metal matrix nanocomposite where graphene sheets are dispersed in matrix material, substantially aligned to be parallel to one another, and in an amount of 0.1-95 vol.%, where multiple graphene sheets contain single-layer graphene sheets selected from pristine graphene material having essentially 0% non-carbon elements, or non-pristine graphene material having 0.001-25 wt.% non-carbon elements where non-pristine graphene is selected from graphene oxide, reduced graphene oxide, graphene fluoride, graphene chloride, graphene bromide, graphene iodide, hydrogenated graphene, nitrogenated graphene, doped graphene, and/or chemically functionalized graphene and the chemically functionalized graphene is not graphene oxide. An INDEPENDENT CLAIM is included for producing a metal matrix nanocomposite. DESCRIPTION OF DRAWING(S) - The drawing shows a flow chart of the process for producing oxidized graphene sheets that entails chemical oxidation/intercalation, rinsing, and high-temperature exfoliation procedures.