• 专利标题:   Electrode comprises laminate of beta-electron conjugated compound film and conductive film which comprises particles of layered material comprising one or plural layers, and modifier or terminal existing on surface of layer body.
  • 专利号:   WO2023002916-A1
  • 发明人:   MURPHY B B, VITALE F, FUJIWAKI M, TORITA T, SUGIURA K, SHIMAZAKI T
  • 专利权人:   MURATA MFG CO LTD, UNIV PENNSYLVANIA
  • 国际专利分类:   A61B005/263, H01M004/02
  • 专利详细信息:   WO2023002916-A1 26 Jan 2023 H01M-004/02 202321 Pages: 35 English
  • 申请详细信息:   WO2023002916-A1 WOJP027742 14 Jul 2022
  • 优先权号:   US223306P

▎ 摘  要

NOVELTY - An electrode (26) comprises a laminate of a pi -electron conjugated compound film (23) and a conductive film (22) which contains particles of a layered material containing one or several layers (l1). The layers (l1) contain a layer metal-based component (I), and a modifier or terminal (T) existing on a surface of the layer metal-based component, where (T) is at least one selected from a hydroxyl group, a fluorine atom, a chlorine atom, an oxygen atom, and a hydrogen atom. The pi -electron conjugated compound film contains a pi -electron conjugated compound containing at least one selected from an aromatic ring, a heteroaromatic ring, a carbon-carbon double bond, a carbon-carbon triple bond, and a carbon-phosphorus double bond. USE - Electrode used as biosignal sensing electrode (claimed) for measuring electroencephalogram, electrocardiogram, electromyogram, and electrical impedance tomography, and used as capacitor electrode, battery electrode, sensor electrode such as gas sensor, biosensor and chemical sensor, antenna electrode. ADVANTAGE - The electrode is capable of maintaining excellent electrode characteristics such as high conductivity for a long period of time. DETAILED DESCRIPTION - An electrode (26) comprises a laminate of a pi -electron conjugated compound film (23) and a conductive film (22) which contains particles (p1) of a layered material containing one or several layers (l1). The layers (l1) contain a layer metal-based component of formula (I): MmXn, where M is at least one metal of Group 3, 4, 5, 6, or 7, X is a carbon atom, a nitrogen atom, or their combination, n is 1-4, and m is less than 5 which is more than the value of n, and a modifier or terminal (T) existing on a surface of the layer metal-based component, where (T) is at least one selected from a hydroxyl group, a fluorine atom, a chlorine atom, an oxygen atom, and a hydrogen atom. The pi -electron conjugated compound film contains a pi -electron conjugated compound containing at least one selected from an aromatic ring, a heteroaromatic ring, a carbon-carbon double bond, a carbon-carbon triple bond, and a carbon-phosphorus double bond. An INDEPENDENT CLAIM is included for manufacture of the electrode, which involves (i) preparing a precursor (I) of a conductive film, (ii) removing at least a portion of atoms from the precursor by using an etching liquid, (iii) washing a intermediate (i1) obtained in the step (ii) with water, (iv) performing an intercalation comprising mixing a intermediate (i2) obtained in the step (iii) with a compound for inter-layer insertion of the intermediate (i2), (v) stirring a intermediate (i3) obtained in the step (iv) in a liquid, (vi) washing a intermediate (i4) obtained in the step (v) with water to obtain particles of a layered material, (vii) forming a conductive film comprising the particles of the layered material on a substrate, and (viii) forming pi -electron conjugated compound film on the conductive film. DESCRIPTION OF DRAWING(S) - The drawing shows a cross-sectional view of action and effect of the electrode. 21Substrate 22Conductive film 23Pi-electron conjugated compound film 25Biological tissue 26Electrode