• 专利标题:   Latex-modified graphene phenolic resin composite for brake pads of cars and trains comprises phenol, aqueous formaldehyde, latex, graphite oxide, and acid catalyst.
  • 专利号:   CN103242622-A
  • 发明人:   SU Z, ZHANG A, ZHAO X
  • 专利权人:   UNIV BEIJING CHEM TECHNOLOGY
  • 国际专利分类:   C08G008/10, C08K013/06, C08K003/04, C08K009/04, C08L061/10, C08L007/02, C08L009/04, C08L009/08
  • 专利详细信息:   CN103242622-A 14 Aug 2013 C08L-061/10 201425 Chinese
  • 申请详细信息:   CN103242622-A CN10192547 23 May 2013
  • 优先权号:   CN10192547

▎ 摘  要

NOVELTY - A latex-modified graphene phenolic resin composite contains 300 pts. wt. phenol, 100-250 pts. wt. 35-40 mass% aqueous formaldehyde, 3-15 pts. wt. 35-45% latex, 0.1-5 pts. wt. graphite oxide, and 1-10 pts. wt. acid catalyst. USE - Latex-modified graphene phenolic resin composite for brake pads (claimed) of cars and trains. ADVANTAGE - The latex-modified graphene phenolic resin composite does not wear easily, has long service life, good heat conductivity, high impact strength, high temperature resistance, and simple post-processing. Preparation is simple, easy to operate, low-cost, and reduces water generation, and avoid defects. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is included for preparation of latex-modified graphene phenolic resin composite mixing 300 pts. wt. phenol, 100-250 pts. wt. 35-40 mass% aqueous formaldehyde with 35-40 mass%, and 1-10 pts. wt. acid catalyst, mechanically stirring, gradually heating to 80 degrees C, adding 0.1-5 pts. wt. graphite oxide, dispersing in solution by ultrasonicating to obtain 0.25-9 mg/ml graphite oxide solution, maintaining temperature at 80-95 degrees C, ultrasonically reacting for 1-3 hours, adding certain amount of formaldehyde and acid catalyst, maintaining temperature at 80-95 degrees C for 1.5-3 hours, adjusting to neutral pH using aqueous sodium hydroxide solution, dropwise adding 3-15 pts. wt. 35-45% latex, adding 0.5-5 g ethylene bis-stearamide, vigorously stirring for 2-20 minutes, vacuum dehydrating until 120-180 degrees C, quickly discharging to observe color of pure solid latex-modified graphene phenolic resin obtained, mixing curing agent, reinforcing fibers, friction modifiers, performance regulators, and filler in mold, hydraulically pressing under vacuum at 150-180 degrees C, and 10-40 MPa for 10-30 minutes, demolding at 160-180 degrees C and preserving heat for 2-6 hours.