• 专利标题:   Degradation of N-nitrosodimethylamine in water body, by adding graphene/iron-based metal-organic framework composite nanomaterials and potassium persulfate to water body to be treated containing N-nitrosodimethylamine, and transferring water body to dark condition for stirring and reacting.
  • 专利号:   CN113307349-A
  • 发明人:   WU Q, SUN M, GU Q, ZHANG Y, ZHANG J, GUO W, WU H
  • 专利权人:   CHINESE ACAD SCI GUANGZHOU CHEM RES INST, GUANGDONG ACAD SCI MICROBIOLOGY INST
  • 国际专利分类:   B01J031/22, C02F001/72, C02F101/34, C02F101/38
  • 专利详细信息:   CN113307349-A 27 Aug 2021 C02F-001/72 202184 Pages: 10 Chinese
  • 申请详细信息:   CN113307349-A CN10427646 21 Apr 2021
  • 优先权号:   CN10427646

▎ 摘  要

NOVELTY - Degradation of N-nitrosodimethylamine (NDMA) involves adding graphene/iron-based metal-organic framework (MOF) composite nanomaterials and potassium persulfate to a water body to be treated containing N-nitrosodimethylamine, and transferring the water body to a dark condition for stirring reaction. USE - Degradation of NDMA in water body. ADVANTAGE - The method: promotes high-efficiency degradation of NDMA through combination of active free radicals in the form of hydroxide radical and sulfate radical on NDMA; and effectively prevents the MOF from agglomeration and being corroded during the catalytic degradation of NDMA. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is included for use of the NDMA degradation method, which involves pretreating disinfected water body to make the concentration of NDMA in the water of less than or equal to 1 mg/L, and the pH of 3-7, then adding graphene/iron-based MOF composite nanomaterials and potassium persulfate to the water body to make the concentration of graphene/iron-based MOF composite nanomaterials of 0.5 mg/mL and the concentration of potassium persulfate of 2 mmol/L, transferring the water body to the dark condition, stirring and reacting at 200 rpm for 90 minutes, heating the water at more than 70 degrees C and stirring for 10-30 minutes, subjecting to natural sedimentation or centrifugal filtration to obtain water body degraded by NDMA.