• 专利标题:   New 3-methyl-6-(4-(1-(4-methylphenyl)-2,2-diphenylethenyl)phenyl)-9H-carbazole-based polymer used for preparing graphene composite material for chemical sensor, bio probe and solid fluorescent material.
  • 专利号:   CN107200832-A, CN107200832-B
  • 发明人:   XU X, LIU P, LI P, MENG Q, YANG W, ZHANG W, HUO X, JI L, HE B, QU Z, HU J, ZONG Y, ZHANG J
  • 专利权人:   ZHENGZHOU TOBACCO RES INST CNDC, UNIV ZHENGZHOU, ZHENGZHOU TOBACCO RES INST CNDC
  • 国际专利分类:   C08G061/12, C08K003/04, C08L065/00
  • 专利详细信息:   CN107200832-A 26 Sep 2017 C08G-061/12 201780 Pages: 19 Chinese
  • 申请详细信息:   CN107200832-A CN10365312 22 May 2017
  • 优先权号:   CN10365312

▎ 摘  要

NOVELTY - A 3-methyl-6-(4-(1-(4-methylphenyl)-2,2-diphenylethenyl)phenyl)-9H-carbazole-based polymer (I), is new. USE - New 3-methyl-6-(4-(1-(4-methylphenyl)-2,2-diphenylethenyl)phenyl)-9H-carbazole-based polymer is used for preparing graphene composite material (all claimed) for chemical sensor, bio probe and solid fluorescent material. ADVANTAGE - The 3-methyl-6-(4-(1-(4-methylphenyl)-2,2-diphenylethenyl)phenyl)-9H-carbazole-based polymer has excellent aggregation-inducing luminescence effect, and provides graphene composite material which is soluble in organic solvent. DETAILED DESCRIPTION - A 3-methyl-6-(4-(1-(4-methylphenyl)-2,2-diphenylethenyl)phenyl)-9H-carbazole-based polymer of formula (I), is new. n=8-20;and R1,R2=1-6C alkyl, 1-6C alkoxy or H. INDEPENDENT CLAIMS are included for the following: (1) preparation of compound (I); (2) graphene composite material, which comprises compound (I) and graphene. The polymer (I) modifies graphene in form of non-covalent bond; and (3) preparation of graphene composite material, which involves preparing solution of polymer (I), mixing graphene oxide dispersion with the polymer (I) solution, adding hydrazine hydrate, reacting, separating, and drying.