• 专利标题:   Manufacture of flexible graphene composite film involves immersing self-supporting flexible graphene film in perchloric acid solution, magnetically-stirring under ice bath condition, and then adding aniline monomer and stirring.
  • 专利号:   CN104592535-A
  • 发明人:   QIAO S
  • 专利权人:   QINGDAO TAIHAODA CARBON MATERIALS CO LTD
  • 国际专利分类:   C08G073/02, C08J005/18, C08K003/04, C08L079/02
  • 专利详细信息:   CN104592535-A 06 May 2015 C08J-005/18 201555 Pages: 4 Chinese
  • 申请详细信息:   CN104592535-A CN10525359 31 Oct 2013
  • 优先权号:   CN10525359

▎ 摘  要

NOVELTY - A graphene solution is filtered using a nylon microporous membrane filter and then vacuum-filtered and stripped, to obtain self-supporting flexible graphene film. The resulting graphene film is immersed in perchloric acid solution into a reactor, magnetically-stirred under ice bath condition, and then aniline monomer is added, and stirred. Ammonium persulfate is added to the reactor, ice-cool-stirred, polymerized, film is removed and washed using perchloric acid solution, and vacuum-dried in an oven, to obtain flexible graphene composite film. USE - Manufacture of flexible graphene composite film (claimed). ADVANTAGE - The method efficiently and economically provides flexible graphene composite film having high super-capacitance and circulation stability. DETAILED DESCRIPTION - A graphene solution is filtered using a nylon microporous membrane filter and then vacuum-filtered and stripped, to obtain self-supporting flexible graphene film having thickness of 10 mu m or less. The resulting graphene film is immersed in perchloric acid solution into a reactor, magnetically-stirred under ice bath condition, and then aniline monomer is added, and stirred for 40 minutes. Ammonium persulfate is added to the reactor, ice-cool-stirred for 25 hours, polymerized, film is removed and washed using 0.1 mol/L perchloric acid solution, and vacuum-dried in an oven at 45 degrees C for 12 hours, to obtain flexible graphene composite film.