• 专利标题:   Preparing graphene composite film used in radio frequency antenna materials, involves mixing graphene micro sheet, low melting point metal salt and solvent to obtain mixed slurry, reducing metal salt to simple metal and forming molten metal, and filling molten metal into graphene micro-sheets.
  • 专利号:   CN113593769-A
  • 发明人:   LIU Z, ZHOU S, XIAO H
  • 专利权人:   NINGBO GRAPHENE INNOVATION CENT CO LTD
  • 国际专利分类:   H01B013/00, H01B005/14
  • 专利详细信息:   CN113593769-A 02 Nov 2021 H01B-013/00 202214 Chinese
  • 申请详细信息:   CN113593769-A CN10765318 07 Jul 2021
  • 优先权号:   CN10765318

▎ 摘  要

NOVELTY - The preparation method of graphene composite film involves: mixing a graphene micro sheet, a low melting point metal salt and a solvent to obtain a mixed slurry; subjecting the mixed slurry to a hot-pressing film-forming process to reduce the low-melting-point metal salt to a simple metal and form a molten metal; and filling the molten metal into the graphene micro-sheets to form a metal microstructure welding graphene to obtain graphene composite film. The melting point of the low-melting-point metal salt is lower than the heat treatment temperature in the hot-pressing film forming process. The solvent includes at least a first component, preferably water and a second component, preferably o-hydroxybenzoic acid, rosin, natural resin, succinic acid or sebacic acid. The solvent further includes a third component, preferably ethanol, N,N-dimethylformamide, or N-methylpyrrolidone. The low melting point metal salt is tin salt, zinc salt, aluminum salt or magnesium salt. USE - Preparation method of graphene composite film used in electronic components of electrode substrates and radio frequency antenna materials. ADVANTAGE - The method provides graphene composite film with high electrical conductivity of 3000-6000 second/cm, reduced contact resistance, increased compactness and improved flatness. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is also included for the graphene composite film prepared by the above process. DESCRIPTION OF DRAWING(S) - The drawing shows a fourth flow chart for preparing a graphene composite film.