• 专利标题:   Preparing graphene-based lithium iron phosphate anode material, involves carrying out co-precipitation of graphene oxide and iron source solution with phosphoric acid, ammonium phosphate or ammonium dihydrogen phosphate, and reacting obtained composite material with lithium carbonate and glucose.
  • 专利号:   CN114171729-A
  • 发明人:   FENG H
  • 专利权人:   HUBEI HUAXI NEW MATERIAL CO LTD
  • 国际专利分类:   H01M010/0525, H01M004/36, H01M004/58, H01M004/583, H01M004/62
  • 专利详细信息:   CN114171729-A 11 Mar 2022 H01M-004/36 202229 Chinese
  • 申请详细信息:   CN114171729-A CN11478554 06 Dec 2021
  • 优先权号:   CN11478554

▎ 摘  要

NOVELTY - Preparing graphene-based lithium iron phosphate anode material, comprises (1) mixing graphene oxide with iron source solution during the preparation of iron phosphate, and subjecting to co-precipitation reaction with phosphoric acid, ammonium phosphate or ammonium dihydrogen phosphate, then washing the reaction product, filtering, vacuum or flash drying, and then calcining and grinding to obtain graphene oxide-iron phosphate composite material, where the amount of graphene oxide added is 1-15% of the amount of iron phosphate, and (2) adding the obtained graphene oxide-iron phosphate composite material, lithium carbonate and glucose into ball mill to grind and disperse evenly, and drying to obtain lithium iron phosphate precursor, then pre-sintering at 250-500 degrees Celsius under hydrogen/argon/nitrogen and other reducing atmosphere for 3-6 hours, sintering at 600-800 degreesC for 6-12 hours and cooling in the furnace to obtain graphene-based lithium iron phosphate anode material. USE - The graphene-based lithium iron phosphate anode material is useful in manufacturing power-type lithium ion batteries. ADVANTAGE - The method improves the dispersibility and uniformity of graphene in the anode material, and thus overcoming the defect that graphene is not easy to disperse in water in the process of preparing anode material.