• 专利标题:   Making graphene oxide-coated carbon fiber-silver-loaded titanium dioxide nanowire array composite material by cleaning carbon fiber with deionized water and ethanol and electrodeposition of graphene oxide solution on carbon fiber.
  • 专利号:   CN105771977-A
  • 发明人:   LI J, LUO C, WANG X, WANG Y, SUN Y, DUAN H, DING C
  • 专利权人:   UNIV JINAN
  • 国际专利分类:   B01J023/50, C02F001/32
  • 专利详细信息:   CN105771977-A 20 Jul 2016 B01J-023/50 201669 Pages: 6 Chinese
  • 申请详细信息:   CN105771977-A CN10162247 22 Mar 2016
  • 优先权号:   CN10162247

▎ 摘  要

NOVELTY - Preparation of graphene oxide-coated carbon fiber-silver-loaded titanium dioxide nanowire array composite material involves (a) ultrasonically cleaning carbon fiber with deionized water and ethanol, carrying out constant-voltage electrodeposition of graphene oxide solution on carbon fiber using platinum wire and silver/silver chloride and drying, and (b) mixing graphene oxide-coated carbon fiber-titanium dioxide nanowire array with silver nitrate solution, ultrasonically dispersing, stirring, carrying out centrifugal separation, washing with deionized water, drying and calcining. USE - Method is useful for preparing graphene oxide-coated carbon fiber-silver-loaded titanium dioxide nanowire array composite material, which is useful in photocatalytic degradation of binary dye wastewater comprising methyl orange and rhodamine B (claimed). ADVANTAGE - The graphene oxide-coated carbon fiber-silver-loaded titanium dioxide nanowire array composite material has high degradation efficiency under visible light of 96% and excellent photocatalytic effect and is easy to separate and recycle. DETAILED DESCRIPTION - Preparation method of graphene oxide-coated carbon fiber-silver-loaded titanium dioxide nanowire array composite material involves (a) ultrasonically cleaning 2-5 cm long carbon fiber with deionized water and ethanol for 30 minutes, carrying out constant-voltage electrodeposition of 3-8 mg/ml graphene oxide solution on carbon fiber as a working electrode using platinum wire as a counter electrode and silver/silver chloride as a reference electrode at 1.2 V for of 90-120 seconds and drying for 10-15 hours to obtain graphene oxide-coated carbon fiber, and (b) mixing 0.4-1.5 g graphene oxide-coated carbon fiber-titanium dioxide nanowire array prepared according to patent number 201410506263.X with 100 ml 0.01-0.1% silver nitrate solution, ultrasonically dispersing for 10 minutes, stirring, carrying out centrifugal separation, washing obtained sample with deionized water, drying at 80-100 degrees C, calcining resulting solid powder in a muffle furnace at 450-500 degrees C for 1.5-2.5 hours to obtain composite material. An INDEPENDENT CLAIM is included for use of graphene oxide-coated carbon fiber-silver-loaded titanium dioxide nanowire array composite material in the photocatalytic degradation of binary dye wastewater comprising methyl orange and rhodamine B.