• 专利标题:   Spinning graphene ribbons into fibers to manufacture graphene ribbon fibers, comprises supplying spin-dope comprising graphene ribbons to spinneret, spinning spin-dope into accrued graphene ribbon fibers, and coagulating accrued fibers.
  • 专利号:   WO2011134717-A1, EP2392700-A1, EP2392700-B1, US2013009337-A1, CN102859054-A, JP2013527332-W, KR2013069604-A, CN102859054-B, JP5607819-B2, RU2012150815-A, US8999212-B2, RU2550850-C2, KR1847802-B1
  • 发明人:   KOENDERS B M, MEERMAN J J, KAMPERMAN S M, WAARBEEK TER R F, JONG DE J, RADIER A A T, OTTO M J, WAARBEEK T R F, JONG D J, MEERMAN YA Y, JONG D Y, OTTO M YA
  • 专利权人:   TEIJIN ARAMID BV, TEIJIN ARAMID BV, TEIJIN ARAMID BV, PROPEX FABRICS GMBH, TEIJIN ARAMID BV, TEIJIN ARAMID BV, TEIJIN ARAMID BV, CONYAR BV
  • 国际专利分类:   D01F009/12, B82Y040/00, D01D005/00, D01D005/06, D01D010/00, D01D010/06, D01D007/00, D01F011/10, D06M010/00, B82B003/00, C01B031/04, D01D004/02
  • 专利详细信息:   WO2011134717-A1 03 Nov 2011 D01F-009/12 201173 Pages: 27 English
  • 申请详细信息:   WO2011134717-A1 WOEP054012 17 Mar 2011
  • 优先权号:   EP161324, KR728156

▎ 摘  要

NOVELTY - The process comprises supplying a spin-dope comprising graphene ribbons to a spinneret, spinning the spin-dope into accrued graphene ribbon fibers, coagulating the accrued graphene ribbon fibers in a coagulation medium to form coagulated graphene ribbon fibers, stripping, optionally neutralizing and washing the coagulated graphene ribbon fibers, and winding the coagulated graphene ribbon fibers. The spin-dope is formed by dissolving the graphene ribbons in a solvent. The coagulation medium flows in the same direction as the accrued graphene ribbon fibers. USE - The process is useful for spinning graphene ribbons into fibers to manufacture graphene ribbon fibers (claimed), which are useful in yarns, nonwovens, membranes and films. ADVANTAGE - The process is capable of accurately spinning the graphene ribbons into fibers thus providing the graphene ribbon fibers with improved performance, excellent flexibility and high strength. DETAILED DESCRIPTION - The process comprises supplying a spin-dope comprising graphene ribbons to a spinneret, spinning the spin-dope into accrued graphene ribbon fibers, coagulating the accrued graphene ribbon fibers in a coagulation medium to form coagulated graphene ribbon fibers, stripping, optionally neutralizing and washing the coagulated graphene ribbon fibers, and winding the coagulated graphene ribbon fibers. The spin-dope is formed by dissolving the graphene ribbons in a solvent. The coagulation medium flows in the same direction as the accrued graphene ribbon fibers. The accrued graphene ribbon fibers and the coagulation medium are transported in a vertically upward direction, a horizontal direction and a vertically downward direction. The coagulation medium is sulfuric acid having a concentration of 90-100%. A temperature of a coagulation bath is 5 degrees C. The accrued graphene ribbon fibers are spun into the coagulation medium via an air gap. DESCRIPTION OF DRAWING(S) - The diagram shows a schematic view of a process for manufacturing graphene ribbon fibers.