• 专利标题:   Preparing a graphene oxide modified starch/chitosan composite packaging film useful in e.g. preparing starch-based film, comprises e.g. adding graphene oxide dispersion liquid to carboxymethyl cellulose solution, obtaining modified graphene oxide small sheet uniform dispersion, drying and cooling.
  • 专利号:   CN115850747-A
  • 发明人:   WANG J, ZHANG S, HE T, WEI D, WU L, LV S
  • 专利权人:   UNIV SHAANXI SCI TECHNOLOGY
  • 国际专利分类:   C08J005/18, C08K003/04, C08K009/04, C08L003/02, C08L039/06, C08L005/08
  • 专利详细信息:   CN115850747-A 28 Mar 2023 C08J-005/18 202339 Chinese
  • 申请详细信息:   CN115850747-A CN11462349 21 Nov 2022
  • 优先权号:   CN11462349

▎ 摘  要

NOVELTY - Preparing a graphene oxide modified starch/chitosan composite packaging film, comprises (1) adding graphene oxide dispersion liquid to carboxymethyl cellulose solution, carrying out ultrasonic treatment, adding urea, stirring uniformly, adjusting the pH value to 9.0-9.5, heating up to 70-80℃ and reacting for 2-3 hours, then adjusting the pH value to 7.0-7.5 to obtain a modified graphene oxide small sheet uniform dispersion, and (2) adding resultant modified graphene oxide small sheet, polyvinylpyrrolidone, and chitosan solution to the gelatinized starch solution, stirring at 70-80℃ for 30-50 minutes, and then pouring, drying, cooling and taking out to obtain the final product. USE - The graphene oxide modified starch/chitosan composite packaging film is useful in preparing starch-based film (claimed), and food and medicine packaging material. ADVANTAGE - The film: is safe, environmentally friendly, economical, capable of blocking water vapor and air and shielding 93.5-96.2 % of ultraviolet radiation; has high mechanical strength, toughness, strong anti-ultraviolet ability, high transmittance, excellent antibacterial effect, water resistance, strong barrier air and water vapor permeability; ensure the content of the oxidation graphene of 0.008-0.01 wt.% of the substrate and prolonged service life.