• 专利标题:   Preparation of chitosan-graphene oxide sponge used as anode in breathable type microorganism fuel cell assembly, by processing graphite oxide suspension, dripping with glacial acetic acid, mixing and adding iron(II) chloride solution.
  • 专利号:   CN108047486-A
  • 发明人:   YU F, WANG C, CHEN D, SHI Y, YAO W, ZHANG F, NI T, HAN S, ZHANG H
  • 专利权人:   SHANGHAI INST TECHNOLOGY
  • 国际专利分类:   C08J009/28, C08K003/04, C08K009/02, C08L005/08, H01M008/16
  • 专利详细信息:   CN108047486-A 18 May 2018 C08J-009/28 201841 Pages: 10 Chinese
  • 申请详细信息:   CN108047486-A CN11464432 28 Dec 2017
  • 优先权号:   CN11464432

▎ 摘  要

NOVELTY - A chitosan-graphene oxide sponge is prepared by adding 2-8 mg/mL graphite oxide suspension into ultrasonic cleaner, ultrasonically processing to obtain graphene oxide solution, taking 80-150 mL graphene oxide solution, dripping 2-6 mL glacial acetic acid, uniformly mixing to obtain mixed solution, dropwise adding 0.1-50 mL of 0.08-0.12 mol/L iron(II) chloride solution, gradually adding 2-10 mL of 0.8-1.2 mol/L sodium benzenesulfinic acid solution, adding 2-10 g chitosan. USE - Method for preparing chitosan-graphene oxide sponge used as anode in breathable type microorganism fuel cell assembly (claimed). ADVANTAGE - The method is simple and has low cost. The sponge has conductivity, biocompatibility, good elasticity, abundant gap structure, large specific surface area, more active sites and easily attached microorganism, prevents sponge degradation by microorganism, and forms ferroferric oxide. DETAILED DESCRIPTION - A chitosan-graphene oxide sponge is prepared by adding 2-8 mg/mL graphite oxide suspension into ultrasonic cleaner, ultrasonically processing to obtain graphene oxide solution, taking 80-150 mL graphene oxide solution, dripping 2-6 mL glacial acetic acid, uniformly mixing to obtain mixed solution, dropwise adding 0.1-50 mL of 0.08-0.12 mol/L iron(II) chloride solution, gradually adding 2-10 mL of 0.8-1.2 mol/L sodium benzenesulfinic acid solution, adding 2-10 g chitosan, uniformly stirring, vacuumizing, removing bubbles to obtain bubble-free slurry, injecting into mold, putting in freeze-dryer, freeze-drying, soaking sample in sodium hydroxide solution to obtain sponge, thermostatic heating, and washing with distilled water. An INDEPENDENT CLAIM is included for application method of chitosan-graphene oxide sponge comprising dissolving chitosan-graphene oxide sponge into microorganism fuel cell in anode chamber, fixing carbon paper material on cathode chamber electrode bracket, separating breathable type microorganism fuel cell cathode chamber and anode chamber by proton exchange membrane, injecting cathode chamber with 100 mL of 0.05 mol/L potassium ferricyanide solution, injecting 50 mL high concentration anaerobic sewage into anode chamber, inoculating electrogenesis microbe, and injecting 50 mL of 0.5 g/L sodium acetate nutrient solution into anode chamber.