• 专利标题:   Absorbent material used for paper diaper, contains acrylic acid/acrylamide/2-acrylamido-2-methylpropanesulfonic acid ternary copolymerized porous superabsorbent resin, edge graphene oxide, and carboxyl-containing carbon nanotubes.
  • 专利号:   CN111215039-A
  • 发明人:   CHEN D
  • 专利权人:   YIJIA FUJIAN SANITARY PROD CO LTD
  • 国际专利分类:   A61F013/53, B01J020/26
  • 专利详细信息:   CN111215039-A 02 Jun 2020 B01J-020/26 202055 Pages: 17 Chinese
  • 申请详细信息:   CN111215039-A CN11146828 21 Nov 2019
  • 优先权号:   CN11146828

▎ 摘  要

NOVELTY - An absorbent material comprises 100-125 pts. wt. polyacrylic acid superabsorbent resin, 45-53 pts. wt. poly(acrylic acid-acrylamide) superabsorbent resin, 30-36 pts. wt. acrylic acid/acrylamide/2-acrylamido-2-methylpropanesulfonic acid ternary copolymerized porous superabsorbent resin, 22-27 pts. wt. graphene oxide, and 8-11 pts. wt. carboxyl-containing carbon nanotubes. The monomer units in macromolecular chain of the poly(acrylic acid-acrylamide) superabsorbent resin includes acrylic acid and acrylamide in a ratio of 10:(8.5-12.5). The monomer units in macromolecular chain of acrylic acid/acrylamide/2-acrylamido-2-methylpropanesulfonic acid ternary copolymerized porous superabsorbent resin includes acrylic acid, acrylamide and 2-acrylamido-2-methylpropanesulfonic acid in a ratio of 10:(7-9):(3.5-4.5). The graphene oxide is edge graphene oxide, and groups grafted on edge of monolithic edge of edge graphene oxide include carboxyl group, hydroxyl group, epoxy group and carbonyl group. USE - Absorbent material is used for paper diaper (claimed). ADVANTAGE - The absorbent material has fast absorption rate, large absorption amount for urine, excellent antibacterial property and effect of adsorbing irritating gases such as ammonia, and low re-infiltration amount, and can effectively reduce urine leakage in actual use, and odor during use. The diaper using the absorbent material provides excellent comfort to baby. DETAILED DESCRIPTION - An absorbent material comprises 100-125 pts. wt. polyacrylic acid superabsorbent resin, 45-53 pts. wt. poly(acrylic acid-acrylamide) superabsorbent resin, 30-36 pts. wt. acrylic acid/acrylamide/2-acrylamido-2-methylpropanesulfonic acid ternary copolymerized porous superabsorbent resin, 22-27 pts. wt. graphene oxide, and 8-11 pts. wt. carboxyl-containing carbon nanotubes. The monomer units in macromolecular chain of the poly(acrylic acid-acrylamide) superabsorbent resin includes acrylic acid and acrylamide in a ratio of 10:(8.5-12.5). The monomer units in macromolecular chain of the acrylic acid/acrylamide/2-acrylamido-2-methylpropanesulfonic acid ternary copolymerized porous superabsorbent resin includes acrylic acid, acrylamide and 2-acrylamido-2-methylpropanesulfonic acid in a ratio of 10:(7-9):(3.5-4.5). The graphene oxide is edge graphene oxide, and groups grafted on edge of monolithic edge of the edge graphene oxide include carboxyl group, hydroxyl group, epoxy group and carbonyl group, in which content of carboxyl group is 37.5-41.8%, and content of hydroxyl group is 29.2-32.4%. INDEPENDENT CLAIMS are included for the following: (1) preparation of absorbent material, which involves mixing polyacrylic acid super absorbent resin, poly(acrylic acid-acrylamide) super absorbent resin, and acrylic acid/acrylamide/2-acrylamido-2-methylpropanesulfonic acid ternary copolymerized porous superabsorbent resin at 55-60 degrees C, vacuum drying until the moisture content is less than 8%, adding graphene oxide and carboxyl-containing carbon nanotubes, adding to crusher, crushing to less than 100 microns, mixing resultant mixture with deionized water for more than 2 hours, filtering, and freeze-drying to moisture content of less than 5% in a freeze dryer; and (2) paper diaper, which comprises a core comprising the absorbent material.