• 专利标题:   Polyethylene long chain of graphene is represented by is chemically bonded, which improve thermal conductivity and mechanical property.
  • 专利号:   CN106893181-A
  • 发明人:   YU X, ZHU K, YANG H
  • 专利权人:   YU X
  • 国际专利分类:   C08F220/02, C08F292/00, C08L023/06, C08L051/10
  • 专利详细信息:   CN106893181-A 27 Jun 2017 C08L-023/06 201765 Pages: 6 Chinese
  • 申请详细信息:   CN106893181-A CN10156555 16 Mar 2017
  • 优先权号:   CN10156555

▎ 摘  要

NOVELTY - Polyethylene long chain of graphene is represented by (I) is chemically bonded. USE - Polyethylene long chain of graphene. ADVANTAGE - The polyethylene long chain of graphene improve thermal conductivity and mechanical property. DETAILED DESCRIPTION - Polyethylene long chain of graphene is represented by (I) is chemically bonded. An INDEPENDENT CLAIM is included for a method for preparing polyethylene long chain of graphene, which involves: (A) adding a closed reactor with a reflux condenser and a magnetic stirrer to an organic solvent and graphene, and replacing with nitrogen and stirring the mixture to 40-70 degrees C to obtain mixture; (B) mixing the obatined mixture with 2-isocyanatoethyl methacrylate and dibutyltin dilaurate and reacted under stirring for 20-90 minutes to obtain a solid product; (C) washing the obtained solid product with ethanol for three times and dried in a vacuum oven to obtain graphene on the surface chemically bonded methacrylate group; (D) sealing the reactor equipped with a reflux condenser and a magnetic stirrer is charged with n-hexane, graphene on the surface chemically bonded methacrylic acid group; (E) catalysing the Ziegler-Natta catalyst, heating at 60-90 degrees C and stirred under pressure of 0.1-1.5MPa for 1-4 hours and purged with nitrogen to obtain ethylene; (F) placing the obtained ethylene into reaction system to carried out for 1-4 hours, and then the reaction is terminated by adding ethanol to obtain a suspension; and (G) centrifuging the obtained suspension to separate the solid precipitate, washed with ethanol and dried in a vacuum oven to obtain chemically bonded polyethylene long chain of graphene.