• 专利标题:   Preparing lithium-sulfur battery positive electrode material involves fully dissolving cobalt nitrate hexahydrate/nickel/iron/copper and zinc nitrate hexahydrate in solvent, stirring and ultrasonically dispersing, adding graphene oxide solution, and ultrasonically stirring to obtain solution A.
  • 专利号:   CN114824215-A
  • 发明人:   FAN C, GAO J, TANG W, LAI H
  • 专利权人:   UNIV CHINA ELECTRONIC SCI TECHNOLOGY
  • 国际专利分类:   H01M004/36, H01M004/525, H01M004/62
  • 专利详细信息:   CN114824215-A 29 Jul 2022 H01M-004/36 202277 Chinese
  • 申请详细信息:   CN114824215-A CN10439746 25 Apr 2022
  • 优先权号:   CN10439746

▎ 摘  要

NOVELTY - Preparing lithium-sulfur battery positive electrode material involves fully dissolving cobalt nitrate hexahydrate/nickel/iron/copper and zinc nitrate hexahydrate in a solvent, stirring and ultrasonically dispersing, then adding graphene oxide solution, and further ultrasonically stirring to obtain solution A and dissolving 2-methylimidazole in the solvent to obtain solution B. The solution A is added to solution B, slowly stirred at 25℃ for 18 hours to obtain a mixed solution, centrifugally washed, and dried to obtain a graphene oxide/zeolite imidazole framework composite material precursor. The precursor is calcined in a nitrogen atmosphere for 2 hours at 900℃, and the heating rate is 5℃ per minute to obtain three-dimensional porous carbon material supporting bimetallic sites. The three-dimensional porous carbon material is mixed with sulfur, ball milled, and then performed a vacuum melting diffusion reaction to obtain product. USE - Method for preparing lithium-sulfur battery positive electrode material. ADVANTAGE - The method improves the cycle stability and multiplying power performance of the battery.