• 专利标题:   Graphene conductive paint comprises water-soluble resin, curing agent, modified polyaniline composite graphene, thickening agent, cross-linking coupling agent, dispersing agent, antifoaming agent, leveling agent and deionized water.
  • 专利号:   CN108912785-A
  • 发明人:   LIN Q
  • 专利权人:   HUNAN GONSION GRAPHITE TECHNOLOGY CO LTD
  • 国际专利分类:   C09D005/24, C09D133/00, C09D175/04, C09D163/00, C09D007/62, C09D007/65
  • 专利详细信息:   CN108912785-A 30 Nov 2018 C09D-005/24 201907 Pages: 14 Chinese
  • 申请详细信息:   CN108912785-A CN10562769 01 Jun 2018
  • 优先权号:   CN10562769

▎ 摘  要

NOVELTY - Graphene conductive paint comprises 40-45 wt.% water-soluble resin and curing agent, 20-28 wt.% modified polyaniline composite graphene, 0.5-2 wt.% thickening agent, 1.5-2.5 wt.% cross-linking coupling agent, 0.5-3 wt.% dispersing agent, 0.1-1 wt.% antifoaming agent, 0.1-1 wt.% leveling agent and deionized water (balance amount), where preparation method of modified polyaniline composite graphene comprises e.g. (i) mixing peanut shell, melamine and 0.8-1.5 mol/l sodium hydroxide solution in a mass ratio of 1-1.3:1.0-1.5:50, making uniform slurry, diluting 2-3 times with water, stirring evenly, discarding bottom layer precipitate to obtain biomass dispersion, (ii) mixing biomass dispersion with graphene oxide solution to obtain reaction solution, reacting hydrothermally at 15-18 degrees C and 180-200 degrees C, dialyzing to obtain modified graphene dispersion, and (iii) polymerizing aniline in modified graphene dispersion to obtain final product. USE - Used as graphene conductive paint. ADVANTAGE - The graphene conductive paint: has excellent storage stability, electrical conductivity, adhesion, impact resistance and flexibility. DETAILED DESCRIPTION - Graphene conductive paint comprises 40-45 wt.% water-soluble resin and curing agent, 20-28 wt.% modified polyaniline composite graphene, 0.5-2 wt.% thickening agent, 1.5-2.5 wt.% cross-linking coupling agent, 0.5-3 wt.% dispersing agent, 0.1-1 wt.% antifoaming agent, 0.1-1 wt.% leveling agent and deionized water (balance amount), where preparation method of modified polyaniline composite graphene comprises (i) mixing peanut shell, melamine and 0.8-1.5 mol/l sodium hydroxide solution in a mass ratio of 1-1.3:1.0-1.5:50, making uniform slurry, diluting 2-3 times with water, stirring evenly, discarding bottom layer precipitate to obtain biomass dispersion, (ii) mixing biomass dispersion with graphene oxide solution to obtain reaction solution, reacting hydrothermally at 15-18 degrees C and 180-200 degrees C, dialyzing to obtain modified graphene dispersion, where biomass in reaction solution is 3-4 mg/ml and content of graphene oxide is 0.5-2 mg/ml, and (iii) polymerizing aniline in modified graphene dispersion to obtain final product. An INDEPENDENT CLAIM is also included for preparing graphene conductive paint comprising mixing water-soluble resin, modified graphene polyaniline composite, thickening agent, crosslinking coupling agent, dispersing agent and deionized water uniformly, adding antifoaming agent and leveling agent and mixing evenly, and packing curing agent separately.