• 专利标题:   Preparation of carbon hollow fiber membrane used in gas separation and purification applications, involves dispersing graphene oxide in solvent, mixing with pore-forming agent dispersion, adding organic membrane material, stirring, spinning obtained solution, drying, and calcining.
  • 专利号:   CN114682101-A, CN114682101-B
  • 发明人:   QIAO S, LIU T, WANG X, MA C, MA N
  • 专利权人:   CHINA PETROLEUM CHEM CORP DALIAN RES, CHINA PETROLEUM CHEM CORP, SINOPEC CORP DALIAN RES INST PETROLEUM
  • 国际专利分类:   B01D067/00, B01D069/02, B01D069/08, B01D071/02
  • 专利详细信息:   CN114682101-A 01 Jul 2022 B01D-069/08 202295 Chinese
  • 申请详细信息:   CN114682101-A CN11599541 30 Dec 2020
  • 优先权号:   CN11599541

▎ 摘  要

NOVELTY - Preparation of carbon hollow fiber membrane involves uniformly mixing copper salt solution and alcoholamine solution, aging for 1-7 days to obtain a pore-forming agent dispersion, ultrasonically dispersing graphene oxide in a solvent, mixing with the pore-forming agent dispersion to obtain a mixture, adding organic membrane material under the condition of heating while stirring to obtain a spinning solution, simultaneously passing the spinning solution as a shell solution and water as a core solution into a spinning head of a spinning machine, spinning in a coagulation bath, naturally drying to obtain hollow fiber membrane precursor, calcining the hollow fiber membrane precursor at 700-1500℃ for 1-4 hours in an inert atmosphere, soaking calcined product in dilute nitric acid, washing and drying. The volume ratio of flow rate of shell solution and core solution is 0.5-5:1. USE - Preparation of carbon hollow fiber membrane (claimed) used in gas separation and purification applications. ADVANTAGE - The method is helpful for reducing carbon hollow fiber film graphitization temperature, enhancing film permeability and mechanical strength. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is included for the carbon hollow fiber membrane.