• 专利标题:   Preparing oligomeric pure graphene material useful in e.g. electric catalytic oxygen reduction reaction, comprises e.g. preparing precursor, carrying out microwave synthesis reaction and subjecting to anhydrous ethanol reagent dispersion.
  • 专利号:   CN106219527-A, CN106219527-B
  • 发明人:   ZHANG D, LIU F, DAI W, CHEN X, LI G, LI H
  • 专利权人:   UNIV SHANGHAI NORMAL
  • 国际专利分类:   C01B031/04, H01M004/90, C01B032/184
  • 专利详细信息:   CN106219527-A 14 Dec 2016 C01B-031/04 201716 Pages: 14 Chinese
  • 申请详细信息:   CN106219527-A CN10593883 26 Jul 2016
  • 优先权号:   CN10593883

▎ 摘  要

NOVELTY - Preparing oligomeric pure graphene material comprises (i) reacting a metal reductant with an alcohol reagent as a carbon source to obtain a precursor; (ii) adding an alkali metal compound to resulting precursor, placing in a microwave reactor and carrying out microwave synthesis reaction; and (iii) removing the reaction product after the completion of the reaction, subjecting to anhydrous ethanol reagent dispersion, adding ultrapure water, regulating the pH of the dispersion to neutral with hydrochloric acid, filtering, washing the product and drying. USE - The oligomeric pure graphene material is useful in electric catalytic oxygen reduction reaction (claimed), energy conversion and storage. DETAILED DESCRIPTION - Preparing oligomeric pure graphene material comprises (i) reacting a metal reductant with an alcohol reagent as a carbon source to obtain a precursor; (ii) adding an alkali metal compound to the resulting precursor, placing in a microwave reactor, flushing inert gas or nitrogen in the reaction chamber, pressurizing to 35 bar, heating at 15-55 degrees C for 5-15 minutes, rising temperature to 160-200 degrees C, holding for 0-60 minutes and carrying out microwave synthesis reaction for 10 minutes; and (iii) removing the reaction product after the completion of the reaction, subjecting to anhydrous ethanol reagent dispersion, adding ultrapure water, regulating the pH of the dispersion to neutral with hydrochloric acid, filtering, washing the product and drying. An INDEPENDENT CLAIM is also included for oligomeric pure graphene material, prepared as mentioned above.