• 专利标题:   Preparing graphene oxide doped iron(II) sulfide nano material composition used in sodium ion battery cathode material includes grinding ferric ammonium oxalate and urea, heat treating, dispersing in deionized water, centrifuging and cooling.
  • 专利号:   CN110190263-A
  • 发明人:   CAO L, WANG R, HUANG J, LI J, XU Z, GUO P, GUO L, LUO X
  • 专利权人:   UNIV SHAANXI SCI TECHNOLOGY
  • 国际专利分类:   B82Y030/00, H01M010/054, H01M004/36, H01M004/58, H01M004/583
  • 专利详细信息:   CN110190263-A 30 Aug 2019 H01M-004/36 201970 Pages: 7 Chinese
  • 申请详细信息:   CN110190263-A CN10514575 14 Jun 2019
  • 优先权号:   CN10514575

▎ 摘  要

NOVELTY - Preparing graphene oxide doped iron(II) sulfide nano material composition comprises (a) mixing analytically pure ferric ammonium oxalate, and urea, and grinding to obtain mixture A, (b) heat treating the mixture A in a low temperature tube furnace at a temperature increase rate of 2-20 degrees C/minute at 500-1200 degrees C for 1-5 hours, cooling and taking out to obtain product B, (c) taking graphene oxide and cetyl trimethylammonium bromide, then adding deionized water to obtain 1-3 mg/ml solution C, and ultrasonically dispersing the graphene oxide, (d) mixing product B with solution C, magnetically stirring, centrifuging, performing suction filtration, and freeze-drying to obtain product D, (e) mixing product D and sulfur source, and grinding to obtain mixture E, and (f) heat treating the mixture E in an argon and hydrogen atmosphere in a low-temperature tube furnace at a rate of 5-10 degrees C/minute at 300-600 degrees C for 30 minutes to 1 hour, and cooling. USE - The nano material is useful in sodium ion battery cathode material (claimed). ADVANTAGE - The method: has two step synthesis method; can increase the dispersion of the graphene sheets so that the graphene and carbon layer are uniformly combined by adding surfactant cetyl trimethylammonium bromide. The material: has good stability, and has high electrochemical sodium storage performance; and is not easy to collapse and break. DETAILED DESCRIPTION - Preparing graphene oxide doped iron(II) sulfide nano material composition comprises (a) mixing analytically pure ferric ammonium oxalate, and urea according to the mass ratio 1:1-7, and grinding to obtain mixture A, (b) heat treating the mixture A in a low temperature tube furnace at a temperature increase rate of 2-20 degrees C/minute at 500-1200 degrees C for 1-5 hours, cooling and taking out to obtain product B, (c) taking graphene oxide and cetyl trimethylammonium bromide in a mass ratio of 3:1, then adding deionized water to obtain 1-3 mg/ml solution C, and ultrasonically dispersing the graphene oxide, (d) mixing product B with solution C, magnetically stirring, centrifuging, performing suction filtration, and freeze-drying to obtain product D, (e) mixing product D and sulfur source in a mass ratio of 1:5-10, and grinding to obtain mixture E, and (f) heat treating the mixture E in an argon and hydrogen atmosphere in a low-temperature tube furnace at a rate of 5-10 degrees C/minute at 300-600 degrees C for 30 minutes to 1 hour, and cooling. An INDEPENDENT CLAIM is also included for graphene oxide doped iron(II) sulfide nano material composition prepared by the above method.