• 专利标题:   Preparing graphene/polypropylene composite powder material useful for SLS, comprises e.g. adding graphite sheet to a mixed solution of concentrated sulfuric acid and nitric acid, stirring, washing solution with deionized water to neutral.
  • 专利号:   CN106146864-A, CN106146864-B
  • 发明人:   YAN C, YANG J, ZHU W, SHI Y, FU Y, WANG Y, WEI Q
  • 专利权人:   GUANGDONG SILVER AGE SCI TECH CO LTD
  • 国际专利分类:   B33Y070/00, C08J003/12, C08K003/04, C08K009/02, C08K009/06, C08L023/12
  • 专利详细信息:   CN106146864-A 23 Nov 2016 C08J-003/12 201720 Pages: 11 Chinese
  • 申请详细信息:   CN106146864-A CN10859919 27 Sep 2016
  • 优先权号:   CN10859919

▎ 摘  要

NOVELTY - Preparing graphene/polypropylene composite powder material comprises e.g. adding graphite sheet to a mixed solution of concentrated sulfuric acid and nitric acid, stirring, washing the solution repeatedly with deionized water to neutral, drying the solution under vacuum at 100 degrees C to constant weight, and then heating-treating; filtering, washing and vacuum drying; adding surfactant and functionalized graphene into an aqueous ethanol solution; sonicating and vigorously stirring; and subjecting the desired dispersion to rotary evaporation under heating, drying and sieving. USE - The graphene/polypropylene composite powder material is useful for SLS (claimed). ADVANTAGE - The graphene/polypropylene composite powder material has uniform shape, suitable particle size and good liquidity. DETAILED DESCRIPTION - Preparing graphene/polypropylene composite powder material comprises (i) adding graphite sheet to a mixed solution of concentrated sulfuric acid and nitric acid, stirring for 16 hours, washing the solution repeatedly with deionized water to neutral, drying the solution under vacuum at 100 degrees C to constant weight, and then heating-treating at 1050 degrees C for 15 seconds to obtain expanded graphite, placing the expanded graphite in a 70 vol% aqueous ethanol solution, carrying out ultrasonic treatment for 8 hours, filtering and drying in vacuum at 100 degrees C to obtain graphene oxide; (ii) homogeneously dispersing the graphene oxide in an aqueous ethanol solution, carrying out ultrasonic treatment and vigorous stirring, adding silane coupling agent slowly, and maintaining at 70-80 degrees C for 20-28 hours, then filtering, washing and vacuum drying at 60 degrees C to constant weight to obtain functionalized graphene; (iii) adding surfactant and functionalized graphene into an aqueous ethanol solution, sonicating and stirring vigorously to obtain a homogeneous dispersion liquid; (iv) selecting polypropylene powder having a particle size of 10-150 mu m and adding polypropylene powder gradually to the homogeneous dispersion while vigorously stirring, sonicating and vigorously stirring for 24 hours to obtain the desired dispersion liquid; and (v) subjecting the desired dispersion to rotary evaporation under heating, drying and sieving.