• 专利标题:   Method for Preparing oxidation resistant copper-based surface enhanced Raman scattering substrate, involves adding alloy strip into hydrochloric acid ethanol solution to remove alloy to obtain nano porous copper, carrying out acid washing on nano porous copper, and washing oxide layer off.
  • 专利号:   CN114150317-A
  • 发明人:   LIU J, NING J, ZHANG L, CHEN C, PAN D
  • 专利权人:   UNIV SHANGHAI
  • 国际专利分类:   B22D011/06, C01B032/19, C22C001/02, C22C001/08, C22C023/00, C22C009/00, C23C026/00, C23F001/22, C23F001/44, C23G001/10, C23G003/02
  • 专利详细信息:   CN114150317-A 08 Mar 2022 C23F-001/22 202232 Chinese
  • 申请详细信息:   CN114150317-A CN11501706 09 Dec 2021
  • 优先权号:   CN11501706

▎ 摘  要

NOVELTY - The method involves smelting and cooling magnesium and copper particles with the purity of 99.99% in a high-frequency induction smelting furnace to obtain an alloy ingot, crushing and melting, spraying alloy liquid onto a rotating copper roller by adopting a single-roller rapid quenching method to prepare an alloy strip, and adding the alloy strip into a hydrochloric acid ethanol solution to remove alloy to obtain nano porous copper. The acid washing is carried out on the nano porous copper, washing an oxide layer off, a graphene oxide solution is spin-coated on the surface of the nano porous copper, and the nano porous copper is immediately transferred to a tubular furnace to carry out thermal reduction in the atmosphere of hydrogen and argon to obtain the reduced graphene oxide/nano porous copper composite substrate. The magnesium and copper particles are quantitatively weighed according to the percentage of constituent atoms of the target alloy. USE - Method for Preparing oxidation resistant copper-based surface enhanced Raman scattering substrate. Uses include but are not limited to biomedicine, surface science, biological sensing, food safety and trace analysis and detection. ADVANTAGE - The method is simple and easy and cost-effective. The prepared substrate surface enhanced Raman scattering capability is excellent, and has strong oxidation resistance and high stability. The obtained reduction-oxidation graphene/nano-porous copper composite substrate has excellent enhancement effect, high detection sensitivity and good air stability. DESCRIPTION OF DRAWING(S) - The drawing shows a schematic diagram of scanning electron microscopy (SEM) image of the reduced graphene oxide/nano porous copper composite strip.