• 专利标题:   Chemical reduction of graphene oxide useful in industrial application for its increased electrical conductance involves using hypophosphorous acid and/or hypophosphite ions as reducing agents and sulfur dioxide, sulfurous acid as catalyst.
  • 专利号:   EP2653445-A1, PL398886-A1, EP2653445-B1
  • 发明人:   LIPINSKA L, JAGIELLO J, KOZINSKI R, BATIJEWSKI R, NAJDEKER E
  • 专利权人:   MATERIALOW ELEKTRONICZNYCH TECHNOLOGY, MATERIALOW ELEKTRONICZNYCH TECHNOLOGY
  • 国际专利分类:   C01B031/04, C01B031/00, B82Y030/00, B82Y040/00, C01B032/184, C01B032/192
  • 专利详细信息:   EP2653445-A1 23 Oct 2013 C01B-031/04 201372 Pages: 12 English
  • 申请详细信息:   EP2653445-A1 EP164131 17 Apr 2013
  • 优先权号:   PL398886

▎ 摘  要

NOVELTY - Method (M1) of chemical reduction of graphene oxide involves subjecting graphene oxide to chemical reduction with hypophosphorous acid and/or hypophosphite ions, in an acidic medium with pH of 0-4.5, using sulfur dioxide, sulfurous acid or its salt as reduction catalyst, and the precipitate of reduced graphene oxide is then separated from the solution. USE - For chemical reduction of graphene oxide useful in industrial application for its increased electrical conductance; reduced graphene oxide is also used in the form of suspensions, layers, and as a powder. ADVANTAGE - Graphene oxide after reduction with method (M1) has a much lower resistivity compared to the value cited in the literature; thus a very high quality of reduced graphene oxide is obtained by the method.