• 专利标题:   Preparing graphene coated magnesium hydroxide nano composite material, comprises e.g. adding graphite oxide to sodium-phosphorus-tungsten vanadium oxides complex solution, adding magnesium acetate and PS-PEG resin, and heating.
  • 专利号:   CN108752634-A
  • 发明人:   PENG G
  • 专利权人:   UNIV NINGBO TECHNOLOGY
  • 国际专利分类:   C08K003/22, C08K009/10
  • 专利详细信息:   CN108752634-A 06 Nov 2018 C08K-009/10 201883 Pages: 7 Chinese
  • 申请详细信息:   CN108752634-A CN10314746 10 Apr 2018
  • 优先权号:   CN10314746

▎ 摘  要

NOVELTY - Preparing graphene coated magnesium hydroxide nano composite material, comprises (a) adding 0.1-0.5 g graphite oxide to 150 ml sodium-phosphorus-tungsten vanadium oxides complex (Na4PW11VO40) (0.1-0.3 M) solution, and stirring at room temperature under speed of 200 revolutions/minute for 10 minutes, (b) adding 1-2 g magnesium acetate and 1 g polystyrene-polyethylene glycol (PS-PEG) resin to the solution prepared in the step (a), adjusting pH to 9-11 with sodium hydroxide, heating, (c) cooling the solution of step (b) to room temperature, introducing into photoreactor, and reacting by irradiating with YLS-2000 laser for 6 hours to obtain black emulsion, (d) placing the black emulsion in 150 ml mixture containing 1:1 deionized water and n-butanol, treating with ultrasonic, filtering, and washing with deionized water until quality is unchanged, and (e) vacuum drying the filter cake at 50-80 degrees C for 8-10 hours, and grinding. USE - The method is useful for preparing graphene coated magnesium hydroxide nano composite material. ADVANTAGE - The method is economical, simple, fast, and environmentally friendly, improves productivity, and does not need any optical catalyst or reducing agent. DETAILED DESCRIPTION - Preparing graphene coated magnesium hydroxide nano composite material, comprises (a) adding 0.1-0.5 g graphite oxide to 150 ml sodium-phosphorus-tungsten vanadium oxides complex (Na4PW11VO40) (0.1-0.3 M) solution, and stirring at room temperature under speed of 200 revolutions/minute for 10 minutes, (b) adding 1-2 g magnesium acetate and 1 g polystyrene-polyethylene glycol (PS-PEG) resin to the solution prepared in the step (a), adjusting pH to 9-11 with sodium hydroxide, heating at 60-80 degrees C under stirring speed of 300 revolutions/minute for 3 hours, (c) cooling the solution of step (b) to room temperature, introducing into a photoreactor, and reacting by irradiating with YLS-2000 laser for 6 hours to obtain black emulsion, (d) placing the black emulsion in 150 ml mixture containing 1:1 deionized water and n-butanol, treating with ultrasonic waves of 30-50 KHz and power of 80-120 W for 2-3 hours, filtering, and washing filter cake with deionized water until quality is unchanged, and (e) vacuum drying the filter cake at 50-80 degrees C for 8-10 hours, and grinding the dried filter cake to obtain graphene-coated magnesium hydroxide nanocomposite.