• 专利标题:   Preparing poly (urea-carbamate)/polyaniline/graphene oxide composite self-healing anticorrosive material involves placing hydrochloric acid solution of aniline in graphene oxide turbid liquid, and stirring in ice-water bath.
  • 专利号:   CN113755001-A, CN113755001-B
  • 发明人:   HAO Q, JU H
  • 专利权人:   UNIV NANJING SCI TECHNOLOGY
  • 国际专利分类:   C08G018/38, C08G018/48, C08G018/66, C08G018/76, C08G073/02, C08K003/04, C08L075/02, C08L075/04, C08L079/02
  • 专利详细信息:   CN113755001-A 07 Dec 2021 C08L-075/04 202211 Chinese
  • 申请详细信息:   CN113755001-A CN10491900 03 Jun 2020
  • 优先权号:   CN10491900

▎ 摘  要

NOVELTY - Preparing poly (urea-carbamate)/polyaniline/graphene oxide composite self-healing anticorrosive material involves placing the hydrochloric acid solution of aniline in the graphene oxide turbid liquid, and stirring for 1-2 hours in ice-water bath to obtain stable mixed solution. The hydrochloric acid solution of ammonium persulfate is continuously added, stirred for 12-24 hours in an ice-water bath, stand, filtered, washed, and freeze-dried to obtain the polyaniline-graphene oxide composite material. The adipic acid dihydrazide N, N-dimethylformamide solution is dropwise added into an N, N-dimethylformamide solution of toluene-2, 4-diisocyanate terminated polypropylene glycol under stirring, reacting under stirring at 115-125℃ for 16-24 hours. The N, N-dimethylformamide dispersion liquid of the polyaniline-graphene oxide composite material is added, stirred at normal temperature for 4-8 hours, and dried to obtain the anticorrosive material. USE - Method for preparing poly (urea-carbamate)/polyaniline/graphene oxide composite self-healing anticorrosive material. ADVANTAGE - The self-healing anticorrosive paint is simple to prepare, is easy to realize industrial production, and has self-healing capability and mechanical property.