• 专利标题:   Producing polymethacrylimide foam in e.g. thermal insulation, comprises mixing reactant of methacrylic acid and acrylonitrile, and/or acrylamide, exposing reaction mixture to UV light, and polymerizing prepolymerization product in container.
  • 专利号:   WO2022071912-A1
  • 发明人:   GUENGOER S, CEBECI H, GUERKAN I, OESKEN I
  • 专利权人:   ROKETSAN ROKET SANAYII TICARET AS
  • 国际专利分类:   C08F002/48, C08K003/013, C08L033/22, C08L033/26
  • 专利详细信息:   WO2022071912-A1 07 Apr 2022 C08K-003/013 202234 Pages: 17 English
  • 申请详细信息:   WO2022071912-A1 WOTR050998 01 Oct 2021
  • 优先权号:   TR015702

▎ 摘  要

NOVELTY - Producing polymethacrylimide (PMI) foam, comprises uniformly mixing a reactant comprising 30-80 wt.% methacrylic acid, and 20-70 wt.% acrylonitrile, and/or 1-3 wt.% acrylamide or their derivatives, as a weight ratio of the components, where the components contain a polymerization initiator, a nucleating agent and a foaming agent in a mixing vessel (3) so that it forms a reaction mixture (4); obtaining a crosslinked foamable prepolymerization product by exposing the reaction mixture to a UV light arriving from a UV source (6) during a pre-polymerization; and obtaining a copolymer PMI block by performing the polymerization reaction of the prepolymerization product in a container at 20-80 degrees C, and subsequently producing foam with a temperature of 100-260 degrees C. USE - The method is useful for producing PMI foam (claimed) which is used in e.g. thermal insulation, packaging, mechanical support, aeronautics, defense, aerospace applications, structural materials, and/or thermal insulation applications for transportation vehicles. ADVANTAGE - The method: provides polymer foam that has density of 40-140 kg/m3, pore size of 50-700 mu m, compressive strength of 0.7-8 MPa, and electrical conductivity of greater than 10-3 S/cm; and shorten the synthesizing time in the polymethacrylimide foam production process. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is also included for a polymer foam obtained by the PMI foam production method. DESCRIPTION OF DRAWING(S) - The figure shows a schematic view of the PMI production method. Liquid components (1) Vessel (3) Reaction mixture (4) UV source (6) Glass plate (9)