• 专利标题:   Production of graphene nanoplatelets used as e.g. additive, involves dispersing expanded flakes of intercalated graphite in dispersing medium and subjecting to exfoliation and size reduction by pumping graphite at preset pressure.
  • 专利号:   WO2015193268-A1, IT1424680-B, EP3157865-A1, CN106660802-A, US2017190583-A1, CN106660802-B
  • 发明人:   CESAREO G, PARRINI M R, RIZZI L G
  • 专利权人:   DIRECTA PLUS SPA, DIRECTA PLUS SPA
  • 国际专利分类:   C01B031/04, C01B000/00, C01B032/182, C01B032/184, C01B031/02
  • 专利详细信息:   WO2015193268-A1 23 Dec 2015 C01B-031/04 201605 Pages: 27 English
  • 申请详细信息:   WO2015193268-A1 WOEP063398 16 Jun 2015
  • 优先权号:   ITMI1123, CN80032693

▎ 摘  要

NOVELTY - Production of graphene nanoplatelets involves expanding flakes of intercalated graphite having lateral size of 500 mu m or less by exposing flakes to 1300-12000 degrees C for a time of less than 2 seconds, dispersing in dispersing medium, and subjecting dispersion to exfoliation and size reduction treatment by high pressure homogenization in which the expanded graphite is pumped at a pressure above 35 MPa through one or more micro-channels or necks. The particles of expanded graphite are subjected to shear stresses and are collided at an energy level from 5-200 Wh/g. USE - Production of graphene nanoplatelets (claimed) used as additive or component of elastomeric compositions for tires, paints and silicone compositions, compositions for treating articles such as textiles. ADVANTAGE - The method economically provides graphene nanoplatelets with very small size, high aspect ratio, low oxygen content, with low energy consumption. DETAILED DESCRIPTION - Production of graphene nanoplatelets having carbon to oxygen ratio of 100:1 or more involves expanding flakes of intercalated graphite having lateral size of 500 mu m or less by exposing flakes to 1300-12000 degrees C for a time of less than 2 seconds, dispersing in dispersing medium, and subjecting to exfoliation and size reduction treatment by high-pressure homogenization in a homogenizer in which the expanded graphite is pumped at a pressure above 35 MPa through one or more micro-channels or necks having a transverse section of not more than 500 mu m. The particles of expanded graphite are subjected to shear stresses and collided at an energy level from 5-200 Wh/g. An INDEPENDENT CLAIM is included for Pristine graphene nanoplatelets, in which at least 90% have lateral size (x, y) of 50 to less than 10000 nm, and a thickness (z) of 0.34-50 nm, and the lateral size being more than the thickness (x, y greater than z).