• 专利标题:   Reparing polyethylene/graphene nanocomposite comprises e.g. reacting dibutyl magnesium with graphene oxide to form intermediate, reacting with titanium tetrachloride to obtain a graphene-based titanium Ziegler-Natta catalyst.
  • 专利号:   CN111100346-A
  • 发明人:   ZHOU H, ZHONG F, HE X, CHEN X, LI Y, QI L
  • 专利权人:   CHINA PETROLEUM CHEM CORP, SINOPEC SHANGHAI PETROCHEMICAL CO LTD
  • 国际专利分类:   C08K003/04, C08L023/06
  • 专利详细信息:   CN111100346-A 05 May 2020 C08L-023/06 202044 Pages: 28 Chinese
  • 申请详细信息:   CN111100346-A CN11246902 25 Oct 2018
  • 优先权号:   CN11246902

▎ 摘  要

NOVELTY - Reparing polyethylene/graphene nanocomposites, comprises reacting dibutyl magnesium with graphene oxide to form an intermediate, reacting the intermediate with titanium tetrachloride to obtain a graphene-based titanium Ziegler-Natta catalyst, using the graphene-based titanium Ziegler-Natta catalyst to catalyzing the polymerization of ethylene to obtain a composite masterbatch, mixing the composite material masterbatch with high-density polyethylene solution. USE - The method is useful for reparing polyethylene/graphene nanocomposites. ADVANTAGE - The nanocomposite: has excellent conductivity; can promotes the crystallization of polyethylene, increases the thickness, crystallinity and crystallization temperature; and enhances the thermal stability of the polyethylene matrix.