• 专利标题:   Preparation of ultra-high-molecular weight polyethylene catalyst support material involves spraying graphene oxide dispersion into liquid nitrogen and atomizing, and adding material to solution containing butyl magnesium chloride.
  • 专利号:   CN104592430-A, CN104592430-B
  • 发明人:   BAI Y, SU E
  • 专利权人:   UNIV LANZHOU, PETROCHINA CO LTD, PETROCHINA CO LTD, UNIV LANZHOU
  • 国际专利分类:   C08F010/02, C08F004/02, C08F004/648, C08F004/651, C08F004/658
  • 专利详细信息:   CN104592430-A 06 May 2015 C08F-010/02 201557 Pages: 12 Chinese
  • 申请详细信息:   CN104592430-A CN10002333 05 Jan 2015
  • 优先权号:   CN10002333

▎ 摘  要

NOVELTY - An aqueous solution of graphene oxide is mixed with silica sol, stirred, and ultrasonically-dispersed, to obtain mixed dispersion. Mixed dispersion is sprayed into liquid nitrogen, atomized, volatile liquid nitrogen is removed and cured product is vacuum-dried, to obtain graphene oxide/silica spherical catalyst support material. The support material is added to mixed solution of tetrahydrofuran and butyl magnesium chloride and stirred, to obtain a reaction product. The reaction product is washed and heated, to obtain ultra-high-molecular weight polyethylene catalyst support material. USE - Preparation of ultra-high-molecular weight polyethylene catalyst support material (claimed). ADVANTAGE - The method efficiently and economically provides ultra-high-molecular weight polyethylene catalyst support material by effectively reducing the polymer molecular chain entanglement. DETAILED DESCRIPTION - An aqueous solution of graphene oxide is mixed with silica sol, stirred, and ultrasonically-dispersed, to obtain mixed dispersion. The mixed dispersion is sprayed into liquid nitrogen, atomized, volatile liquid nitrogen is removed and cured product is vacuum-dried in a vacuum chamber to remove moisture, to obtain sample. The obtained sample is heated, to obtain graphene oxide/silica spherical catalyst support material. The support material is added to mixed solution of tetrahydrofuran and butyl magnesium chloride, and stirred at 50-80 degrees C for 12-48 hours, to obtain a reaction product. The reaction product is washed to remove excess butyl magnesium chloride, and then heated at 400-800 degrees C for 30-120 minutes under an argon atmosphere, to obtain ultra-high-molecular weight polyethylene catalyst support material.