• 专利标题:   Preparing power lithium-ion battery cathode material comprises preparing germanium or tin oxide/fast lithium-ion conductor, coating thin carbon layer on the outer surface of the above prepared material, performing carbothermic reduction, and reacting with phosphate, selenide or telluride.
  • 专利号:   CN113942984-A
  • 发明人:   ZHENG X, XU C, XU J, QIU L, LI G, HU X
  • 专利权人:   UNIV CHONGQING TECHNOLOGY
  • 国际专利分类:   C01B019/00, C01B019/04, C01B025/08, C01B032/05, C01B032/194, C01G025/00, H01M010/0525, H01M004/1397
  • 专利详细信息:   CN113942984-A 18 Jan 2022 C01B-025/08 202263 Chinese
  • 申请详细信息:   CN113942984-A CN11114054 23 Sep 2021
  • 优先权号:   CN11114054

▎ 摘  要

NOVELTY - Preparing power lithium-ion battery cathode material comprises preparing porous metal oxide, or preparing porous fast lithium-ion conductor, loading fast lithium-ion conductor into the porous-channel metal oxide, or loading the porous metal oxide into porous-channel fast lithium-ion conductor to prepare metal oxide/fast lithium-ion conductor, coating thin carbon layer on the outer surface of metal oxide/fast lithium-ion conductor and performing carbothermic reduction simultaneously to prepare metal oxide/fast lithium-ion conductor- thin carbon layer, and reacting with phosphate, selenide or telluride to obtain phosphide or selenide or telluride of germanium or tin/fast lithium-ion conductor- thin carbon layer as a anchored on the surface of the graphene sheet. USE - The method is useful for preparing power lithium-ion battery cathode material. ADVANTAGE - The method: solves the problems of large volume change, fast capacity decay and low first coulomb efficiency in the existing method in a targeted manner through the structural design of graphene/carbon co-coating and ion conductor modification. DETAILED DESCRIPTION - Preparing power lithium-ion battery cathode material comprises preparing porous metal oxide (MOx), or preparing porous fast lithium-ion conductor, loading fast lithium-ion conductor into the porous-channel metal oxide, or loading the porous metal oxide into porous-channel fast lithium-ion conductor to prepare metal oxide/fast lithium-ion conductor, coating thin carbon layer on the outer surface of metal oxide/fast lithium-ion conductor and performing carbothermic reduction simultaneously to prepare metal oxide/fast lithium-ion conductor-thin carbon layer, and reacting with phosphate, selenide or telluride to obtain phosphide or selenide or telluride of germanium or tin/fast lithium-ion conductor-thin carbon layer as anchored on the surface of the graphene sheet. M = Ge or Sn; and x = integer.