• 专利标题:   High-strength plastics comprise modified substrate prepared by pre-treating substrate, and surface modifying, and anticorrosive coating comprising epoxy resin, ethylene glycol monobutyl ether, silane coupling agent and modified graphene.
  • 专利号:   CN112358638-A
  • 发明人:   ZHANG X
  • 专利权人:   ZHANG X
  • 国际专利分类:   C08J007/04, C08J007/12, C08K003/32, C08K005/053, C08K009/04, C08L023/06, C08L003/02, C08L003/08, C08L051/06, C09D163/00, C09D005/08, C09D007/62, C09D007/63
  • 专利详细信息:   CN112358638-A 12 Feb 2021 C08J-007/04 202124 Pages: 10 Chinese
  • 申请详细信息:   CN112358638-A CN11238562 09 Nov 2020
  • 优先权号:   CN11238562

▎ 摘  要

NOVELTY - A high-strength plastics comprise a modified substrate and an anticorrosive coating applied on surface of the modified substrate. The modified substrate is prepared by pre-treating substrate, and carrying out surface modification using silane coupling agent (A). The anticorrosive coating comprises 60-70 pts. wt. epoxy resin, 25-30 pts. wt. ethylene glycol monobutyl ether, 30-40 pts. wt. silane coupling agent (B) and 10-15 pts. wt. modified graphene. USE - High-strength plastics. ADVANTAGE - The degradable and environmentally-friendly plastics have excellent strength, water resistance and corrosion resistance, and can be prepared by easy and simple process. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is included for preparation of the plastics, which involves ultrasonically dispersing zirconium phosphate and n-butylamine for 1-1.2 hours, stirring, reacting for 20-22 hours, drying to obtain modified zirconium phosphate, stirring modified zirconium phosphate, cationic starch, corn starch and glycerin for 30-40 minutes, extruding, granulating to obtain modified starch, mixing modified starch, compatibilizer, polyethylene and corn starch for 40-50 minutes, extruding, granulating, molding to obtain pre-treated substrate, placing in acetone solution, ultrasonically processing for 20-30 minutes, mechanically polishing surface of resultant, washing, drying, soaking in silane coupling agent (A) solution at 110-120 degrees C for 20-30 minutes to obtain modified substrate, ultrasonically dispersing graphene oxide and zinc nitrate solution for 20-30 minutes, adding phosphoric acid and sodium dihydrogen phosphate, microwave heating to 65-70 degrees C for 15-20 minutes, add the filler, stirring for 25 minutes, separating, washing with deionized water, calcining at 90-100 degrees C for 5-7 minutes to obtain modified graphene, mixing epoxy resin and ethylene glycol monobutyl ether for 20-30 minutes, adding silane coupling agent (B) and modified graphene, stirring for 8-10 hours, reacting, immersing in modified substrate in resultant solution at 30-40 degrees C for 12-15 hours.