• 专利标题:   Composite catalyst used for aromatic hydrogenation dealkylation process, comprises graphene oxide and zinc oxide, loaded palladium metal, and sodium, potassium and silver metals.
  • 专利号:   CN106345463-A
  • 发明人:   GAO Y, TAN H, ZHANG M, YU H
  • 专利权人:   SHANDONG HENGXIN TECHNOLOGY DEV CO LTD
  • 国际专利分类:   B01J023/06, B01J023/60, B01J032/00, B01J035/10, C07C015/04, C07C015/06, C07C015/08, C07C004/18, C10G045/52
  • 专利详细信息:   CN106345463-A 25 Jan 2017 B01J-023/60 201730 Pages: 6 Chinese
  • 申请详细信息:   CN106345463-A CN10730887 26 Aug 2016
  • 优先权号:   CN10730887

▎ 摘  要

NOVELTY - Composite catalyst comprises graphene oxide and zinc oxide, loaded palladium metal, and sodium, potassium and silver metals, where the content of palladium metal is 1-3 wt.% and the total content of sodium, potassium and silver is 0.1-0.5 wt.%. USE - Composite catalyst used for aromatics hydrogenation dealkylation process. ADVANTAGE - The composite catalyst has low temperature hydrogenation activity and good stability, and reduces the deposition speed. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is included for a method for preparing composite catalyst which involves: (A) mixing the graphene oxide aqueous solution with zinc oxide, adding ammonium carbonate and polyvinyl alcohol, milling and mixing the powder and drying to prepare composite carrier; (B) using direct current magnetron sputtering for loading of palladium metal to composite carrier; and (C) immersing the composite carrier in palladium salt solution and salt solution of sodium, potassium and silver under acidic conditions, and drying to prepare the composite catalyst.