• 专利标题:   Preparing graphene/graphene oxide-carbon nanotube composite material by dispersing graphene/graphene oxide in ethanol and water mixed solution, adding iron-containing nanocatalyst and sulfur-containing substance and hydrothermally reacting.
  • 专利号:   CN108069420-A, CN108069420-B
  • 发明人:   JIANG X, TIAN R
  • 专利权人:   JIANGSU XFNANO MATERIALS TECHNOLOGY CO
  • 国际专利分类:   C01B032/162, C01B032/194, C01B032/198
  • 专利详细信息:   CN108069420-A 25 May 2018 C01B-032/194 201850 Pages: 7 Chinese
  • 申请详细信息:   CN108069420-A CN11191049 24 Nov 2017
  • 优先权号:   CN11191049

▎ 摘  要

NOVELTY - The method for preparing graphene/graphene oxide-carbon nanotube composite material involves (a) ultrasonically dispersing graphene/graphene oxide in mixed solution of ethanol and water to obtain a dispersion liquid, (b) adding iron-containing nanocatalyst and sulfur-containing substance to the dispersion liquid, (c) hydrothermally reacting the mixed dispersion liquid, naturally cooling to room temperature, centrifuging the product, washing and drying to obtain a reaction product, (d) carrying out deposition on the reaction product by a chemical vapor deposition method, dividing the deposition into 3 temperature zones including a gasification zone, a constant temperature zone (I) and a constant temperature zone (II), introducing argon and hydrogen, introducing carbon source so that the carbon source sequentially passes through the gasification zone, constant-temperature zone (I) and constant-temperature zone (II) and growing nanocarbon on the surface of the reaction product. USE - Method is useful for preparing graphene/graphene oxide-carbon nanotube composite material. ADVANTAGE - The composite material has excellent mechanical and electrical performance. DETAILED DESCRIPTION - The dispersion liquid in the step (a) has graphene/graphene oxide content of 0.1-5 mg/ml. The temperature in the gasification zone is 150-600 degrees C under vacuum conditions and the temperature of the constant temperature zone (I) and a constant temperature zone (II) is 1100-1400 degrees C.