• 专利标题:   Preparing ozone catalyst useful for removing odor, comprises e.g. preparing manganese source solution using potassium permanganate, mixing with graphene oxide dispersion, reacting in hydrothermal kettle, and treating with ozone.
  • 专利号:   CN111804296-A
  • 发明人:   CUI D, ZHAO K, TONG Q, YUAN J, CAI T, JIN C
  • 专利权人:   SHANGHAI NAT ENG RES CENT NANOTECHNOLOGY
  • 国际专利分类:   B01D053/48, B01D053/86, B01J023/34, B01J037/03, B01J037/10, B01J037/12, B01J037/16
  • 专利详细信息:   CN111804296-A 23 Oct 2020 B01J-023/34 202093 Pages: 6 Chinese
  • 申请详细信息:   CN111804296-A CN10661839 10 Jul 2020
  • 优先权号:   CN10661839

▎ 摘  要

NOVELTY - Preparing ozone catalyst, comprises (i) dissolving potassium permanganate in deionized water, and stirring continuously for 10-30 minutes to obtain manganese source solution A with a mass concentration of 5%, (ii) ultrasonically dispersing graphene oxide in deionized water, adding rare earth metal additive, and ultrasonicating for 30 minutes to obtain graphene oxide dispersion B with a mass concentration of 0.3-1%, (iii) mixing the above solution A and dispersion B, and reacting in a hydrothermal kettle at 100-140 degrees C for 1-3 hours, where the mass ratio of graphene oxide to potassium permanganate is 1:40-1:15, and (iv) filtering the obtained precipitate, washing, drying at 60-100 degrees C, and treating with ozone in a tube furnace for 1 hour to obtain an ozone catalyst, where graphene oxide is used as a reducing agent, manganese dioxide is used as an active component, and a rare earth element is used as a catalytic promoter. USE - The ozone catalyst is useful for removing odor (claimed). ADVANTAGE - The method: produces ozone catalyst having increased specific surface area and improved catalytic activity; has simple process; and is suitable for large-scale production. DETAILED DESCRIPTION - INDEPENDENT CLAIMS are also included for: (1) ozone catalyst prepared by the above method; and (2) use method of the ozone catalyst for removing odor, where methyl mercaptan ozone degradation performance is tested in a fixed bed device under the following test conditions including total gas flow rate of 100 ml/minute, a reaction temperature of 25 degrees C, methyl mercaptan initial concentration of 100 ppm, ozone initial concentration of 500 ppm and balance amount of air, and 0.1 g of catalyst.