• 专利标题:   Preparing carbon nanotube and graphene-modified light-resistant aqueous acrylate-based resin coating comprises adding water, wt. emulsifier, acrylic acid and gelatin, stirring, carrying out emulsification and insulating.
  • 专利号:   CN108624183-A
  • 发明人:   DUAN B, WANG Q, ZHAO Y, DIAO S, ZHANG M, LI Y, LUAN J
  • 专利权人:   UNIV YANTAI
  • 国际专利分类:   C08F002/26, C08F002/30, C08F220/14, C08F220/18, C08F220/20, C09D133/14, C09D007/61
  • 专利详细信息:   CN108624183-A 09 Oct 2018 C09D-133/14 201875 Pages: 10 Chinese
  • 申请详细信息:   CN108624183-A CN10556380 01 Jun 2018
  • 优先权号:   CN10556380

▎ 摘  要

NOVELTY - Preparing carbon nanotube and graphene-modified light-resistant aqueous acrylate-based resin coating comprises (i) adding 50-65 pts. wt. water, 0.3-0.7 pts. wt. emulsifier, 1-2 pts. wt. acrylic acid and 5-6 pts. wt. gelatin aqueous solution having a mass concentration of 3 to 5%, stirring at 40 degrees C for 70 minutes, adding monomer A, carrying out emulsification for 40-90 minutes, when the temperature is increased from 70 degrees C through the reflux water to 80 degrees C, dropwise adding 0.3-0.6 pts. wt. ammonium persulfate for 1 hour, insulating for 1-3 hours to obtain a core layer emulsion, (ii) adding B monomer to the core layer emulsion, 5-6 pts. wt. gelatin solution with a concentration of 3-5% and 0.3-0.7 pts. wt. ammonium persulfate for 1-2 hours, insulating at 85-95 degrees C for 1.5-2 hours, adding 0.5-1.0 pts. wt. cross-linking agent and 1.2 pts. wt. light-resistant material, insulating for 1-2 hours, reducing the temperature to 50 degrees C. USE - The method is useful for preparing carbon nanotube and graphene-modified light-resistant aqueous acrylate-based resin coating. ADVANTAGE - The method is simple and convenient. DETAILED DESCRIPTION - Preparing carbon nanotube and graphene-modified light-resistant aqueous acrylate-based resin coating comprises (i) adding 50-65 pts. wt. water, 0.3-0.7 pts. wt. emulsifier, 1-2 pts. wt. acrylic acid and 5-6 pts. wt. gelatin aqueous solution having a mass concentration of 3 to 5%, stirring at 40 degrees C for 70 minutes, adding monomer A, carrying out emulsification for 40-90 minutes, when the temperature is increased from 70 degrees C through the reflux water to 80 degrees C, drop wise adding 0.3-0.6 pts. wt. ammonium persulfate for 1 hour, insulating for 1-3 hours to obtain a core layer emulsion, where ammonium persulfate is dissolved with 6 pts. wt. water, the monomer A comprises 3-6 pts. wt. hydroxyethyl methacrylate, 4-10 pts. wt. hydroxybutyl acrylate and 3.5-5.5 pts. wt. hydroxyethyl acrylate, (ii) adding B monomer to the core layer emulsion, 5-6 pts. wt. gelatin solution with a concentration of 3-5% and 0.3-0.7 pts. wt. ammonium persulfate for 1-2 hours, insulating at 85-95 degrees C for 1.5-2 hours, adding 0.5-1.0 pts. wt. cross-linking agent and 1.2 pts. wt. light-resistant material, insulating for 1-2 hours, reducing the temperature to 50 degrees C, where the ammonium persulfate is dissolved with 5 pts. wt. water, the B Monomer comprises 3-5 pts. wt. hydroxyethyl methacrylate, 3.5-5.5 pts. wt. ethyl acrylate and 3.5-6.5 pts. wt. methyl methacrylate.